Herein, 2D V2NTx MXene/rGO nanocomposites were synthesised by preferential etching Al layer from the V2AlN MAX precursor utilizing NaF and HCl solution and a reducing agent. With the introduction of rGO, the highest intense peak shifted towards a lower 2θ value, indicating an increase in d-spacing in V2NTx MXene/rGO composites. Accordion-like MXene/rGO structure was observed with layer spacing from 0.20 to 2.1 μm in V2NTx/rGO nanocomposites. Introducing rGO in V2NTx MXene protects the surface from undesirable reactions and oxidation. Due to the quantum confinement effect, the Tauc absorption band gaps ranged from 4.75 to 5.11 eV. The surface area and pore diameter of V2NTx MXene were enhanced after the introduction of rGO, which were 172.52 m2/g and 182.82 nm, respectively. However, a significant improvement in the electrochemical measurement of V2NTx MXene was observed with rGO introduction with the highest specific capacitance (Cp) of 5.69–126.11 F/g in cyclic voltammetry and 19.22–622.97 F/g in galvanostatic charge-discharge in 1M H2SO4. The cyclic stability was maintained at 88.3 % after 10,000 continuous charge and discharge cycles. The Energy and power densities ranged from 2.66 to 864.44 Whkg−1 and 499.59–2499.73 kWkg−1, respectively. The (V2NTx)0.25/rGO0.75 sample showed a corrosion rate of 1.5 × 10−8 mm/y, which is 1.46 and 4.46 times less than V2NTx MXene and rGO. In addition to providing an abundance of active sites for electric double-layer capacitors and pseudocapacitance, rGO gave V2NTx MXene/rGO with increased porosity and an interwoven laminar network, both of which are essential for electrolyte access and charge transmission.