Reticular Materials for Photocatalysis.

Abstract

Photocatalysis leverages solar energy to overcome the thermodynamic barrier, enabling efficient chemical reactions under mild conditions. It can greatly reduce reliance on traditional energy sources and has attracted significant research interest. Reticular materials, including metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), represent a class of crystalline materials constructed from molecular building blocks linked by coordination and covalent bonds, respectively. Reticular materials function as heterogeneous catalysts, combining well-defined structures and high tailorability akin to homogeneous catalysts. In this review, the regulation of light absorption, charge separation, and surface reactions in the photocatalytic process through precise molecular-level design based on the features of reticular materials is elaborated. Notably, for MOFsmicroenvironment modulation around catalytic sites affects photocatalytic performance is delved, with emphasis on their unique dynamic and flexible microenvironments. For COFs, the inherent excitonic effects due to their fully organic nature is discussed and highlight the strategies to regulate excitonic effects for charge- and/or energy-transfer-mediated photocatalysis. Finally, the current challenges and future directions in this field, aiming to provide a comprehensive understanding of how reticular materials can be optimized for enhanced photocatalysis is discussed.