{"title":"An advanced deep learning-driven Terahertz metamaterial sensor for distinguishing different red wines","authors":"Jingxiao Yu, Hongbin Pu, Da-Wen Sun","doi":"10.1016/j.cej.2024.158177","DOIUrl":null,"url":null,"abstract":"Terahertz time-domain spectroscopy (THz-TDS) encounters two issues in the detection field, which refer to the detection target for solid samples caused by the strong absorption of water and the large content target substance led by the low sensitivity. Fortunately, terahertz metamaterial (THz-MM) that can carry liquid samples and amplify signals solves the above problems well. In addition, the THz-MM can achieve the detection of trace substances through the resonance peak shift generated by designing suitable structures. However, since most researchers focus on designing complex structures rather than analyzing data, deep learning (DL) that can mine new features from original features and construct decision models is used to research the rich information in THz-MM sensor data. In the current research, a flexible transmissive THz-MM in the shape of a circle (‘O’ shape) was designed by depositing the gold on the polyimide substrate. Firstly, the structures referring to substrate thickness (ST), metal thickness (MT) and ring width (RW) were optimized, and the performances referring to principle, stability and sensitivity were evaluated. Next, the best THz-MM (ST: 16 µm, MT: 0.2 µm, RW: 6 µm) was prepared and characterized from morphology, thickness and consistency. Then, different concentrations of anthocyanins (R<sup>2</sup>: 0.9982) and tannic acid (R<sup>2</sup>: 0.9736) were successfully predicted by combining the resonance peak shifts. Finally, resonance peak descriptors were constructed and combined with DL referring to a fully connected neural network (FCNN) model to successfully identify different varieties of red wines (<em>Precision</em>: 91.11 %; <em>Recall</em>: 90.74 %, <em>F</em>1-<em>score</em>: 90.83 %; <em>Accuracy</em>: 90.74 %). Overall, the current research presents an advanced DL-driven THz-MM sensor, which promotes the process of THz-TDS technology in the food detection field","PeriodicalId":270,"journal":{"name":"Chemical Engineering Journal","volume":"20 1","pages":""},"PeriodicalIF":13.3000,"publicationDate":"2024-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Engineering Journal","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1016/j.cej.2024.158177","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Terahertz time-domain spectroscopy (THz-TDS) encounters two issues in the detection field, which refer to the detection target for solid samples caused by the strong absorption of water and the large content target substance led by the low sensitivity. Fortunately, terahertz metamaterial (THz-MM) that can carry liquid samples and amplify signals solves the above problems well. In addition, the THz-MM can achieve the detection of trace substances through the resonance peak shift generated by designing suitable structures. However, since most researchers focus on designing complex structures rather than analyzing data, deep learning (DL) that can mine new features from original features and construct decision models is used to research the rich information in THz-MM sensor data. In the current research, a flexible transmissive THz-MM in the shape of a circle (‘O’ shape) was designed by depositing the gold on the polyimide substrate. Firstly, the structures referring to substrate thickness (ST), metal thickness (MT) and ring width (RW) were optimized, and the performances referring to principle, stability and sensitivity were evaluated. Next, the best THz-MM (ST: 16 µm, MT: 0.2 µm, RW: 6 µm) was prepared and characterized from morphology, thickness and consistency. Then, different concentrations of anthocyanins (R2: 0.9982) and tannic acid (R2: 0.9736) were successfully predicted by combining the resonance peak shifts. Finally, resonance peak descriptors were constructed and combined with DL referring to a fully connected neural network (FCNN) model to successfully identify different varieties of red wines (Precision: 91.11 %; Recall: 90.74 %, F1-score: 90.83 %; Accuracy: 90.74 %). Overall, the current research presents an advanced DL-driven THz-MM sensor, which promotes the process of THz-TDS technology in the food detection field
期刊介绍:
The Chemical Engineering Journal is an international research journal that invites contributions of original and novel fundamental research. It aims to provide an international platform for presenting original fundamental research, interpretative reviews, and discussions on new developments in chemical engineering. The journal welcomes papers that describe novel theory and its practical application, as well as those that demonstrate the transfer of techniques from other disciplines. It also welcomes reports on carefully conducted experimental work that is soundly interpreted. The main focus of the journal is on original and rigorous research results that have broad significance. The Catalysis section within the Chemical Engineering Journal focuses specifically on Experimental and Theoretical studies in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. These studies have industrial impact on various sectors such as chemicals, energy, materials, foods, healthcare, and environmental protection.