Organic Permeable Base Transistors—Reliable Large-Scale Anodization for High Frequency Devices

IF 19 1区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Advanced Functional Materials Pub Date : 2025-01-16 DOI:10.1002/adfm.202418270
Amric Bonil, Ghader Darbandy, Jan Frede, Moritz Flemming, Christian Matthus, Lautaro Petrauskas, Juan Wang, Kyung-Geun Lim, Hans Kleemann
{"title":"Organic Permeable Base Transistors—Reliable Large-Scale Anodization for High Frequency Devices","authors":"Amric Bonil,&nbsp;Ghader Darbandy,&nbsp;Jan Frede,&nbsp;Moritz Flemming,&nbsp;Christian Matthus,&nbsp;Lautaro Petrauskas,&nbsp;Juan Wang,&nbsp;Kyung-Geun Lim,&nbsp;Hans Kleemann","doi":"10.1002/adfm.202418270","DOIUrl":null,"url":null,"abstract":"<p>Organic permeable base transistors (OPBTs) have demonstrated impressive performance and potential in various applications, such as display driving circuits, light-emitting transistors, and logic circuits requiring high-frequency operation. However, large-scale implementation is hindered by fabrication reliability and repeatability issues, a problem also common with other types of organic transistors, leading to reliance on exceptional “hero” devices. To address this challenge, an electrochemical anodization process is scaled up and optimized for OPBTs to produce consistent performance across an entire 15 cm × 15 cm wafer. By controlling the Al base oxidation, an 87% yield of functional devices and a median transconductance of <i>d</i>−3<i>is achieved</i> S, proving that the anodization process does not degrade the device performance. Additionally, anodization reduces leakage current to below <i>d</i>−9A, increasing the current gain to a median of 10<sup>6</sup>, and decreases the oxide capacitance (<i>C</i><sub>ox</sub>) without affecting the transconductance (<i>g</i><sub>m</sub>), resulting in a driving-voltage normalized unity-gain cutoff frequency (<i>f</i><sub><i>T</i></sub>/<i>V</i>) of up to 2.6 MHzV<sup>−1</sup>. The validity of the experimental results is confirmed through properly calibrated technology computer-aided design (TCAD) simulations, which rely on DC and small-signal AC analysis of OPBTs, based on the underlying physical equations.</p>","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"35 17","pages":""},"PeriodicalIF":19.0000,"publicationDate":"2025-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adfm.202418270","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Functional Materials","FirstCategoryId":"88","ListUrlMain":"https://advanced.onlinelibrary.wiley.com/doi/10.1002/adfm.202418270","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

Organic permeable base transistors (OPBTs) have demonstrated impressive performance and potential in various applications, such as display driving circuits, light-emitting transistors, and logic circuits requiring high-frequency operation. However, large-scale implementation is hindered by fabrication reliability and repeatability issues, a problem also common with other types of organic transistors, leading to reliance on exceptional “hero” devices. To address this challenge, an electrochemical anodization process is scaled up and optimized for OPBTs to produce consistent performance across an entire 15 cm × 15 cm wafer. By controlling the Al base oxidation, an 87% yield of functional devices and a median transconductance of d−3is achieved S, proving that the anodization process does not degrade the device performance. Additionally, anodization reduces leakage current to below d−9A, increasing the current gain to a median of 106, and decreases the oxide capacitance (Cox) without affecting the transconductance (gm), resulting in a driving-voltage normalized unity-gain cutoff frequency (fT/V) of up to 2.6 MHzV−1. The validity of the experimental results is confirmed through properly calibrated technology computer-aided design (TCAD) simulations, which rely on DC and small-signal AC analysis of OPBTs, based on the underlying physical equations.

Abstract Image

Abstract Image

Abstract Image

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
有机渗透基晶体管-高频器件可靠的大规模阳极氧化
有机渗透基晶体管(OPBT)在各种应用中,如显示驱动电路、发光晶体管和需要高频操作的逻辑电路中,表现出了令人印象深刻的性能和潜力。然而,大规模应用却受到制造可靠性和可重复性问题的阻碍,这也是其他类型有机晶体管普遍存在的问题,导致对特殊 "英雄 "器件的依赖。为了应对这一挑战,我们对电化学阳极氧化工艺进行了放大和优化,使 OPBT 在整个 15 厘米 × 15 厘米的晶片上产生一致的性能。通过控制铝基氧化,实现了 87% 的功能器件产量和 d-3 的中值跨导,证明阳极氧化工艺不会降低器件性能。此外,阳极氧化还能将漏电流降低到 d-9A 以下,将电流增益提高到中值 106,并在不影响跨导 (gm) 的情况下降低氧化电容 (Cox),从而使驱动电压归一化后的单位增益截止频率 (fT/V) 高达 2.6 MHzV-1。实验结果的正确性通过适当校准的技术计算机辅助设计(TCAD)模拟得到了证实,该模拟依赖于基于基本物理方程的 OPBT 直流和小信号交流分析。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Advanced Functional Materials
Advanced Functional Materials 工程技术-材料科学:综合
CiteScore
29.50
自引率
4.20%
发文量
2086
审稿时长
2.1 months
期刊介绍: Firmly established as a top-tier materials science journal, Advanced Functional Materials reports breakthrough research in all aspects of materials science, including nanotechnology, chemistry, physics, and biology every week. Advanced Functional Materials is known for its rapid and fair peer review, quality content, and high impact, making it the first choice of the international materials science community.
期刊最新文献
A Platform Material for Melt Electrowriting: Shape Memory Poly(Alkylene Terephthalate)s with Tunable Thermo-Mechanical Properties In Situ Grown Multi-Functional Siloxane-Based Organic–Inorganic Hybrid Matrix toward Robust Sulfide-Lithium Metal Interface for All-Solid-State Batteries Catheter-Deployable Janus Hydrogel Actuator for Magnetically Guided Biliary Repair With Machine-Learning Assisted Mechano-Sensing Competition Between Charge Collection and Recombination Governing the Fill Factor in Phase-Separated All-Polymer Solar Cells Fine-Tuning Electrostatic Interactions and Dispersion of a Guest Component Toward High-Performance Polymer Solar Cells
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1