Scanning Thermal Microscopy Method for Self-Heating in Nonlinear Devices and Application to Filamentary Resistive Random-Access Memory

IF 16 1区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY ACS Nano Pub Date : 2025-01-29 DOI:10.1021/acsnano.4c12784
Nele Harnack, Sophie Rodehutskors, Bernd Gotsmann
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Abstract

Devices with a highly nonlinear resistance-voltage relationship are candidates for neuromorphic computing, which can be achieved by highly temperature dependent processes like ion migration. To explore the thermal properties of such devices, Scanning Thermal Microscopy (SThM) can be employed. However, due to the nonlinearity, the high resolution and quantitative method of AC-modulated SThM cannot readily be used. To this end, an extended nonequilibrium scheme for temperature measurement using SThM is proposed, with which the self-heating of nonlinear devices is studied without the need for calibrating the tip–sample contact for a specific material combination, geometry or roughness. Both a DC and an AC voltage are applied to the device, triggering a periodic temperature rise, which enables the simultaneous calculation of the tip–sample thermal resistance and the device temperature rise. The method is applied to HfO2-based RRAM devices, in which the kinetic processes of filamentary switching are governed by temperature. We image temperature and propagation of thermal waves and extract properties like the number of current filaments, thermal confinement and thermal cross-talk.

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用于非线性器件自加热的扫描热显微镜方法及其在丝状电阻式随机存取存储器中的应用
具有高度非线性电阻-电压关系的器件是神经形态计算的候选者,这可以通过离子迁移等高度依赖温度的过程来实现。为了探索这些器件的热性能,可以使用扫描热显微镜(SThM)。然而,由于交流调制SThM的非线性特性,其高分辨率和定量方法难以实现。为此,提出了一种扩展的非平衡方案,用于使用SThM进行温度测量,该方案研究了非线性器件的自加热,而无需针对特定的材料组合,几何形状或粗糙度校准尖端样品接触。在器件上同时施加直流和交流电压,触发周期性温升,从而可以同时计算尖端样品热阻和器件温升。将该方法应用于基于hfo2的RRAM器件,其中丝状开关的动力学过程受温度控制。我们对热波的温度和传播进行成像,并提取电流细丝数量、热约束和热串扰等特性。
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来源期刊
ACS Nano
ACS Nano 工程技术-材料科学:综合
CiteScore
26.00
自引率
4.10%
发文量
1627
审稿时长
1.7 months
期刊介绍: ACS Nano, published monthly, serves as an international forum for comprehensive articles on nanoscience and nanotechnology research at the intersections of chemistry, biology, materials science, physics, and engineering. The journal fosters communication among scientists in these communities, facilitating collaboration, new research opportunities, and advancements through discoveries. ACS Nano covers synthesis, assembly, characterization, theory, and simulation of nanostructures, nanobiotechnology, nanofabrication, methods and tools for nanoscience and nanotechnology, and self- and directed-assembly. Alongside original research articles, it offers thorough reviews, perspectives on cutting-edge research, and discussions envisioning the future of nanoscience and nanotechnology.
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