Phase equilibria in the Y-B and Y-Fe-B systems

IF 5.3 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Intermetallics Pub Date : 2025-02-01 Epub Date: 2024-12-04 DOI:10.1016/j.intermet.2024.108588
Chengliang Qiu, Shuhong Liu, Yanwen Liu, Yong Du
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Abstract

Phase diagram of the Y-B system and isothermal sections of the Y-Fe-B system at 600 and 800 °C were investigated using X-ray diffraction (XRD), electron probe microanalysis (EPMA) and differential scanning calorimetry (DSC) on the annealed alloys. In the Y-B system, temperature of L↔(αY)+YB2 was determined to be 1294 °C. YB6 was confirmed to be a stoichiometric compound at 1000 °C. For the isothermal section of the Y-Fe-B system at 600 °C, five ternary compounds (τ14, τ6) and 10 three-phase regions were observed. But there were six ternary compounds (τ16) and 18 three-phase regions in the isothermal section at 800 °C. Ternary phases were measured to be stoichiometric compounds and the measured solubility of the third element in the binary phases was mostly below 0.5 at.% at both 600 and 800 °C.
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Y-B和Y-Fe-B体系的相平衡
采用x射线衍射(XRD)、电子探针微分析(EPMA)和差示扫描量热法(DSC)对退火合金进行了600℃和800℃时Y-B体系的相图和Y-Fe-B体系的等温切片研究。在Y-B系统中,确定L↔(αY)+YB2的温度为1294℃。YB6在1000℃时被证实为化学计量化合物。在600℃时,Y-Fe-B体系的等温截面上观察到5个三元化合物(τ1-τ4, τ6)和10个三相区。而在800℃等温剖面上,出现了6个三元化合物(τ1-τ6)和18个三相区。测定的三元相为化学计量化合物,测定的三元相中第三元素的溶解度大多低于0.5 at。%在600和800°C。
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来源期刊
Intermetallics
Intermetallics 工程技术-材料科学:综合
CiteScore
7.80
自引率
9.10%
发文量
291
审稿时长
37 days
期刊介绍: This journal is a platform for publishing innovative research and overviews for advancing our understanding of the structure, property, and functionality of complex metallic alloys, including intermetallics, metallic glasses, and high entropy alloys. The journal reports the science and engineering of metallic materials in the following aspects: Theories and experiments which address the relationship between property and structure in all length scales. Physical modeling and numerical simulations which provide a comprehensive understanding of experimental observations. Stimulated methodologies to characterize the structure and chemistry of materials that correlate the properties. Technological applications resulting from the understanding of property-structure relationship in materials. Novel and cutting-edge results warranting rapid communication. The journal also publishes special issues on selected topics and overviews by invitation only.
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