Thermostimulated Formation of Silver Nanoaggregates and Their Effect on the Photoluminescence of Nd3+ Ions in Barium Phosphate Glass

IF 0.6 4区 材料科学 Q4 MATERIALS SCIENCE, CERAMICS Glass and Ceramics Pub Date : 2025-01-08 DOI:10.1007/s10717-025-00716-2
M. P. Vetchinnikov, G. Yu. Shakhgildyan, E. S. Ignat’eva, A. I. Ozerova, K. I. Runina, V. N. Sigaev
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Abstract

Phosphate glasses with a high concentration of Nd3+ ions are key components for the development of efficient near-infrared (NIR) laser systems. The sensitization of Nd3+ ion luminescence in BaO–P2O5 glass using Ag nanoaggregates is investigated in this study. The results show that the thermally stimulated formation of \({\text{Ag}}_{m}^{n+}\) molecular clusters allow a 15-fold enhancement of the photoluminescence intensity of Nd3+ ions, whereas the formation of plasmonic nanoparticles (NPs) did not achieve such an enhancement. These results open new perspectives for controlling the properties of phosphate glasses and improving the efficiency of laser systems.

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热刺激银纳米聚集体的形成及其对磷酸钡玻璃中Nd3+离子光致发光的影响
具有高浓度Nd3+离子的磷酸盐玻璃是开发高效近红外(NIR)激光系统的关键部件。本文研究了银纳米聚集体对BaO-P2O5玻璃中Nd3+离子发光的增感作用。结果表明,\({\text{Ag}}_{m}^{n+}\)分子团簇的热激发形成使Nd3+离子的光致发光强度增强了15倍,而等离子体纳米粒子(NPs)的形成没有实现这种增强。这些结果为控制磷酸盐玻璃的性质和提高激光系统的效率开辟了新的前景。
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来源期刊
Glass and Ceramics
Glass and Ceramics 工程技术-材料科学:硅酸盐
CiteScore
1.00
自引率
16.70%
发文量
85
审稿时长
6-12 weeks
期刊介绍: Glass and Ceramics reports on advances in basic and applied research and plant production techniques in glass and ceramics. The journal''s broad coverage includes developments in the areas of silicate chemistry, mineralogy and metallurgy, crystal chemistry, solid state reactions, raw materials, phase equilibria, reaction kinetics, physicochemical analysis, physics of dielectrics, and refractories, among others.
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