Prof. Masatoshi Shibuya, Souta Yuruka, Prof. Yoshihiko Yamamoto
{"title":"Frontispiz: Generation of Bis(pentafluorophenyl)boron Enolates from Alkynes and Their Catalyst-Free Alkyne Coupling","authors":"Prof. Masatoshi Shibuya, Souta Yuruka, Prof. Yoshihiko Yamamoto","doi":"10.1002/ange.202580462","DOIUrl":null,"url":null,"abstract":"<p>Catalyst-free alkyne couplings using bis(pentafluorophenyl)boron enolates are reported by Masatoshi Shibuya, Souta Yuruka and Yoshihiko Yamamoto in their Communication (e202417910). The strongly Lewis acidic boron center activates a carbon–carbon triple bond, enabling C−C bond formation between the boron enolate and the alkyne.\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 4","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202580462","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ange.202580462","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Catalyst-free alkyne couplings using bis(pentafluorophenyl)boron enolates are reported by Masatoshi Shibuya, Souta Yuruka and Yoshihiko Yamamoto in their Communication (e202417910). The strongly Lewis acidic boron center activates a carbon–carbon triple bond, enabling C−C bond formation between the boron enolate and the alkyne.
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