Synergistic mechanism of metal ions and sodium N-oleoylsarcosinate on flotation separation of lepidolite from feldspar

IF 4.7 1区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Transactions of Nonferrous Metals Society of China Pub Date : 2025-01-01 Epub Date: 2025-01-23 DOI:10.1016/S1003-6326(24)66680-X
Guo-yuan XIANG , Rui-hua FAN , Wen-tao ZHU , Wei SUN , Ren-ji ZHENG , Zhi-yong GAO
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Abstract

The combined reagents of sodium N-oleoylsarcosinate (SNOS) with metal ions (Ca(II), Mg(II), Cu(II), and Pb(II)) was employed to facilitate the separation of lepidolite from feldspar. The synergistic interaction mechanism of this combined reagent was systematically investigated via contact angle measurements, AFM, FTIR, species distribution calculations, and DFT calculations. The results suggested that Ca(II) exhibited the best selectivity for activating lepidolite flotation. SNOS was chemically adsorbed on the Ca(II)-activated lepidolite surface with an adsorption energy of −1248.91 kJ/mol while a lower adsorption energy of −598.84 kJ/mol of SNOS on Ca(II)-activated feldspar was calculated. Therefore, this combination of SNOS and Ca(II) is a promising reagent scheme for the efficient recovery of lithium from aluminosilicate ore.
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金属离子与n -油基肌酸钠在锂云石与长石浮选分离中的协同作用机理
采用n -油基肌酸钠(SNOS)与金属离子(Ca(II)、Mg(II)、Cu(II)、Pb(II))的组合试剂,促进了锂云母与长石的分离。通过接触角测量、原子力显微镜(AFM)、红外光谱(FTIR)、物种分布计算和DFT计算,系统地研究了该组合试剂的协同作用机理。结果表明,Ca(II)对活化锂云石浮选表现出最好的选择性。SNOS在Ca(II)活化的锂云石表面的化学吸附能为- 1248.91 kJ/mol,而在Ca(II)活化的长石表面的吸附能较低,为- 598.84 kJ/mol。因此,SNOS和Ca(II)的组合是一种很有前途的从铝硅酸盐矿石中高效回收锂的试剂方案。
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来源期刊
CiteScore
7.40
自引率
17.80%
发文量
8456
审稿时长
3.6 months
期刊介绍: The Transactions of Nonferrous Metals Society of China (Trans. Nonferrous Met. Soc. China), founded in 1991 and sponsored by The Nonferrous Metals Society of China, is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology, including mineral processing, extraction metallurgy, metallic materials and heat treatments, metal working, physical metallurgy, powder metallurgy, with the emphasis on fundamental science. It is the unique preeminent publication in English for scientists, engineers, under/post-graduates on the field of nonferrous metals industry. This journal is covered by many famous abstract/index systems and databases such as SCI Expanded, Ei Compendex Plus, INSPEC, CA, METADEX, AJ and JICST.
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