An eco-friendly catalytic pretreatment using recyclable CuFeO2 catalyst for enhancing the production of bio-based ethanol and jet fuel

IF 5.8 2区 生物学 Q1 AGRICULTURAL ENGINEERING Biomass & Bioenergy Pub Date : 2025-03-01 Epub Date: 2025-02-01 DOI:10.1016/j.biombioe.2025.107668
Rui Zhang , Can Zhu , Yu Jiang , Yuming Ni , Nan Huang , Wanyun Tang , Minghui Fan , Quanxin Li
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Abstract

The development of green and efficient biomass pretreatment methods is of great significance for the conversion of lignocellulosic biomass into biofuels. The main objective of this work is to demonstrate a novel recyclable CuFeO2 catalytic pretreatment way that can be used to promote the production of bioethanol and bio-jet fuel from corncob. Compared to untreated corncob, the biomass pretreated with CuFeO2 catalyst showed higher sugar production (39.9 %) and higher ethanol production (35.6 %). Especially, the directional transformation of corncob to bio-jet fuel has been achieved by integrating biomass fermentation and catalytic synthesis process. The ethanol conversion of 94.3 % and jet fuel selectivity of 64.7 % were obtained in the process of biofuel synthesis. Based on biomass characterizations, catalyst characterizations and reactive oxygen species analysis, the possible role and mechanism of the CuFeO2 catalytic pretreatment were outlined. The CuFeO2 catalytic pr-treatment can be carried out by using the recyclable catalyst at atmospheric pressure and room temperature, which may provide a useful pretreatment way for promoting the biofuel production from lignocellulosic biomass.

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利用可回收CuFeO2催化剂进行生态友好型催化预处理,以提高生物基乙醇和航空燃料的生产
开发绿色高效的生物质预处理方法对木质纤维素生物质转化为生物燃料具有重要意义。本工作的主要目的是展示一种新的可回收CuFeO2催化预处理方法,该方法可用于促进玉米芯生产生物乙醇和生物喷气燃料。与未处理玉米芯相比,CuFeO2催化剂预处理后的生物质产糖率(39.9%)和乙醇率(35.6%)均有所提高。特别是将生物质发酵与催化合成相结合,实现了玉米芯向生物喷气燃料的定向转化。在生物燃料合成过程中,乙醇转化率为94.3%,航空燃料选择性为64.7%。基于生物质表征、催化剂表征和活性氧分析,概述了CuFeO2催化预处理可能的作用和机理。可回收催化剂可在常压和室温条件下进行CuFeO2催化预处理,为促进木质纤维素生物质生产生物燃料提供了有益的预处理途径。
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来源期刊
Biomass & Bioenergy
Biomass & Bioenergy 工程技术-能源与燃料
CiteScore
11.50
自引率
3.30%
发文量
258
审稿时长
60 days
期刊介绍: Biomass & Bioenergy is an international journal publishing original research papers and short communications, review articles and case studies on biological resources, chemical and biological processes, and biomass products for new renewable sources of energy and materials. The scope of the journal extends to the environmental, management and economic aspects of biomass and bioenergy. Key areas covered by the journal: • Biomass: sources, energy crop production processes, genetic improvements, composition. Please note that research on these biomass subjects must be linked directly to bioenergy generation. • Biological Residues: residues/rests from agricultural production, forestry and plantations (palm, sugar etc), processing industries, and municipal sources (MSW). Papers on the use of biomass residues through innovative processes/technological novelty and/or consideration of feedstock/system sustainability (or unsustainability) are welcomed. However waste treatment processes and pollution control or mitigation which are only tangentially related to bioenergy are not in the scope of the journal, as they are more suited to publications in the environmental arena. Papers that describe conventional waste streams (ie well described in existing literature) that do not empirically address ''new'' added value from the process are not suitable for submission to the journal. • Bioenergy Processes: fermentations, thermochemical conversions, liquid and gaseous fuels, and petrochemical substitutes • Bioenergy Utilization: direct combustion, gasification, electricity production, chemical processes, and by-product remediation • Biomass and the Environment: carbon cycle, the net energy efficiency of bioenergy systems, assessment of sustainability, and biodiversity issues.
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