Maryam Naseer, Sadia Nazir, Abida Kausar, Muhammad Abid Rashid, Muhammad Usman, Rehana Naseer, Jibran Iqbal
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引用次数: 0
Abstract
HKUST-1, graphene oxide (GO), and their composite (HKUST-1/GO) were synthesized and characterized via FTIR, XRD, SEM, BET, and TGA. The composite was evaluated for the adsorption of Astrazon Pink FG, Cationic Red 3R, and Basic Yellow 28 dyes. Batch adsorption experiments were conducted to optimize key parameters, with maximum removal observed under the following conditions: AP FG (pH 9, contact time 80 min, 30 °C), CR 3R (pH 11, contact time 80 min, 30 °C), and BY 28 (pH 10, contact time 20 min, 30 °C). The HKUST-1/GO composite exhibited high removal efficiencies of 82.35 % (AP FG), 78.73 % (CR 3R), and 75.89 % (BY 28), with corresponding maximum adsorption capacities of 7.445 mg/g, 6.42 mg/g, and 5.58 mg/g, respectively. The adsorption followed a pseudo-second-order model and well described by Freundlich, Langmuir, Halsey, and Temkin isotherms models. Thermodynamic parameters confirmed spontaneous, exothermic dyes adsorption onto HKUST-1/GO, effectively treating industrial effluent.
期刊介绍:
Chemical engineering enables the transformation of natural resources and energy into useful products for society. It draws on and applies natural sciences, mathematics and economics, and has developed fundamental engineering science that underpins the discipline.
Chemical Engineering Science (CES) has been publishing papers on the fundamentals of chemical engineering since 1951. CES is the platform where the most significant advances in the discipline have ever since been published. Chemical Engineering Science has accompanied and sustained chemical engineering through its development into the vibrant and broad scientific discipline it is today.