Spectroscopic Ellipsometry and Correlated Studies of AlGaN-GaN HEMTs Prepared by MOCVD.

IF 4.3 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY Nanomaterials Pub Date : 2025-01-22 DOI:10.3390/nano15030165
Yanlian Yang, Yao Liu, Yaoze Li, Manika Tun Nafisa, Zhe Chuan Feng, Lianshan Wang, Jeffrey Yiin, Lingyu Wan, Benjamin Klein, Ian Ferguson, Wenhong Sun
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Abstract

A series of AlGaN/GaN high-electron-mobility transistor (HEMT) structures, with an AlN thin buffer, GaN thick layer and Al0.25Ga0.75N layer (13-104 nm thick), is prepared by metal-organic chemical vapor deposition and investigated via multiple techniques. Spectroscopic ellipsometry (SE) and temperature-dependent measurements and penetrative analyses have achieved significant understanding of these HEMT structures. Bandgaps of AlGaN and GaN are acquired via SE-deduced relationships of refraction index n and extinguish coefficient k vs. wavelength λ in a simple but straightforward way. The optical constants of n and k, and the energy gap Eg of AlGaN layers, are found slightly altered with the variation in AlGaN layer thickness. The Urbach energy EU at the AlGaN and GaN layers are deduced. High-resolution X-ray diffraction and calculations determined the extremely low screw dislocation density of 1.6 × 108 cm-2. The top AlGaN layer exhibits a tensile stress influenced by the under beneath GaN and its crystalline quality is improved with the increase in thickness. Comparative photoluminescence (PL) experiments using 266 nm and 325 nm two excitations reveal and confirm the 2DEG within the AlGaN-GaN HEMT structures. DUV (266 nm) excitation Raman scattering and calculations acquired carrier concentrations in compatible AlGaN and GaN layers.

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MOCVD制备AlGaN-GaN hemt的椭圆偏振光谱及相关研究。
采用金属有机化学气相沉积技术制备了一系列具有AlN薄缓冲层、GaN厚层和Al0.25Ga0.75N (13-104 nm厚)的AlGaN/GaN高电子迁移率晶体管(HEMT)结构,并通过多种技术进行了研究。光谱椭偏仪(SE)和温度相关测量以及渗透分析已经对这些HEMT结构有了重要的了解。利用se推导出的折射率n和消光系数k与波长λ的关系,简单而直接地获得了AlGaN和GaN的带隙。随着AlGaN层厚的变化,AlGaN层的光学常数n和k以及能隙Eg略有变化。推导了AlGaN和GaN层的乌尔巴赫能量EU。高分辨率x射线衍射和计算确定了极低的螺位错密度为1.6 × 108 cm-2。上层AlGaN受下层GaN的拉应力影响,其结晶质量随厚度的增加而改善。在266 nm和325 nm两种激发下的比较光致发光(PL)实验揭示并证实了AlGaN-GaN HEMT结构中的2DEG。DUV (266 nm)激发拉曼散射和计算得到相容的AlGaN和GaN层中的载流子浓度。
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来源期刊
Nanomaterials
Nanomaterials NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
8.50
自引率
9.40%
发文量
3841
审稿时长
14.22 days
期刊介绍: Nanomaterials (ISSN 2076-4991) is an international and interdisciplinary scholarly open access journal. It publishes reviews, regular research papers, communications, and short notes that are relevant to any field of study that involves nanomaterials, with respect to their science and application. Thus, theoretical and experimental articles will be accepted, along with articles that deal with the synthesis and use of nanomaterials. Articles that synthesize information from multiple fields, and which place discoveries within a broader context, will be preferred. There is no restriction on the length of the papers. Our aim is to encourage scientists to publish their experimental and theoretical research in as much detail as possible. Full experimental or methodical details, or both, must be provided for research articles. Computed data or files regarding the full details of the experimental procedure, if unable to be published in a normal way, can be deposited as supplementary material. Nanomaterials is dedicated to a high scientific standard. All manuscripts undergo a rigorous reviewing process and decisions are based on the recommendations of independent reviewers.
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