Effects of Degassing Treatment on the Dielectric Properties of XLPE Insulation Used in High-Voltage DC Power Cables.

IF 4.9 3区 工程技术 Q1 POLYMER SCIENCE Polymers Pub Date : 2025-02-06 DOI:10.3390/polym17030431
Man Ding, Qingfeng Zheng, Jiahe Wang, Weifeng He, Chao Dai, Dingjun Wen
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Abstract

Cross-linked polyethylene power cables are widely used in high-voltage DC transmission lines, owing to their good dielectric and physical-chemical properties. However, the production process of XLPE involves cross-linking and degassing, in which the cross-linking process produces a variety of cross-linking by-products, and the changes in the properties of the cable insulation caused by the degassing process are not well understood. XLPE samples were degassed at 90 °C for 7 and 14 days in this paper, and the main by-products were found to be α-methylstyrene, acetophenone, and cumyl alcohol, the contents of which all declined after the degassing treatment. The results show that the space charge density, the leakage current under a high electric field at different temperatures, and the breakdown strength of the XLPE samples all decreased after the degassing treatment. On the other hand, the XLPE sample after 7 days' degassing had the lowest conductivity and the highest conductance activation, and the space charge density and the charge decay rate as well as the breakdown strength after 7 days' degassing differed little from the 14-day treated sample, demonstrating that the 7-day degassing treatment at 90 °C would be enough to achieve superior performance.

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脱气处理对高压直流电缆用交联聚乙烯绝缘介电性能的影响
交联聚乙烯电力电缆因其良好的介电性能和物理化学性能,被广泛应用于高压直流输电线路中。然而,交联聚乙烯的生产过程包括交联和脱气,其中交联过程会产生多种交联副产物,而脱气过程引起的电缆绝缘性能变化尚不十分清楚。本文对 XLPE 样品在 90 °C 下脱气 7 天和 14 天,发现主要副产物为 α-甲基苯乙烯、苯乙酮和积醇,脱气处理后其含量均有所下降。结果表明,经过脱气处理后,XLPE 样品的空间电荷密度、不同温度下高电场下的泄漏电流和击穿强度都有所下降。另一方面,经过 7 天脱气处理的 XLPE 样品具有最低的电导率和最高的电导活化率,而且 7 天脱气处理后的空间电荷密度、电荷衰减率和击穿强度与经过 14 天处理的样品差别不大,这表明在 90 ℃ 下经过 7 天脱气处理就足以获得优异的性能。
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来源期刊
Polymers
Polymers POLYMER SCIENCE-
CiteScore
8.00
自引率
16.00%
发文量
4697
审稿时长
1.3 months
期刊介绍: Polymers (ISSN 2073-4360) is an international, open access journal of polymer science. It publishes research papers, short communications and review papers. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Polymers provides an interdisciplinary forum for publishing papers which advance the fields of (i) polymerization methods, (ii) theory, simulation, and modeling, (iii) understanding of new physical phenomena, (iv) advances in characterization techniques, and (v) harnessing of self-assembly and biological strategies for producing complex multifunctional structures.
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