{"title":"Effects of Degassing Treatment on the Dielectric Properties of XLPE Insulation Used in High-Voltage DC Power Cables.","authors":"Man Ding, Qingfeng Zheng, Jiahe Wang, Weifeng He, Chao Dai, Dingjun Wen","doi":"10.3390/polym17030431","DOIUrl":null,"url":null,"abstract":"<p><p>Cross-linked polyethylene power cables are widely used in high-voltage DC transmission lines, owing to their good dielectric and physical-chemical properties. However, the production process of XLPE involves cross-linking and degassing, in which the cross-linking process produces a variety of cross-linking by-products, and the changes in the properties of the cable insulation caused by the degassing process are not well understood. XLPE samples were degassed at 90 °C for 7 and 14 days in this paper, and the main by-products were found to be α-methylstyrene, acetophenone, and cumyl alcohol, the contents of which all declined after the degassing treatment. The results show that the space charge density, the leakage current under a high electric field at different temperatures, and the breakdown strength of the XLPE samples all decreased after the degassing treatment. On the other hand, the XLPE sample after 7 days' degassing had the lowest conductivity and the highest conductance activation, and the space charge density and the charge decay rate as well as the breakdown strength after 7 days' degassing differed little from the 14-day treated sample, demonstrating that the 7-day degassing treatment at 90 °C would be enough to achieve superior performance.</p>","PeriodicalId":20416,"journal":{"name":"Polymers","volume":"17 3","pages":""},"PeriodicalIF":4.7000,"publicationDate":"2025-02-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymers","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.3390/polym17030431","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
Cross-linked polyethylene power cables are widely used in high-voltage DC transmission lines, owing to their good dielectric and physical-chemical properties. However, the production process of XLPE involves cross-linking and degassing, in which the cross-linking process produces a variety of cross-linking by-products, and the changes in the properties of the cable insulation caused by the degassing process are not well understood. XLPE samples were degassed at 90 °C for 7 and 14 days in this paper, and the main by-products were found to be α-methylstyrene, acetophenone, and cumyl alcohol, the contents of which all declined after the degassing treatment. The results show that the space charge density, the leakage current under a high electric field at different temperatures, and the breakdown strength of the XLPE samples all decreased after the degassing treatment. On the other hand, the XLPE sample after 7 days' degassing had the lowest conductivity and the highest conductance activation, and the space charge density and the charge decay rate as well as the breakdown strength after 7 days' degassing differed little from the 14-day treated sample, demonstrating that the 7-day degassing treatment at 90 °C would be enough to achieve superior performance.
期刊介绍:
Polymers (ISSN 2073-4360) is an international, open access journal of polymer science. It publishes research papers, short communications and review papers. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Polymers provides an interdisciplinary forum for publishing papers which advance the fields of (i) polymerization methods, (ii) theory, simulation, and modeling, (iii) understanding of new physical phenomena, (iv) advances in characterization techniques, and (v) harnessing of self-assembly and biological strategies for producing complex multifunctional structures.