Pengfei Liu, Lingxiao He, Wei Shen, Siliang You, Zhiqiang Song, Bo Du, Sarfaraz Ahmed, Hong Yan, Ye Sha, Xiang Li
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引用次数: 0
Abstract
The design of easily modifiable nanohoops with favourable photophysical properties is crucial for their applications. Here, carborane-based boron-clusters are linked to meta-cycloparaphenylenes (mCPPs) as pendants through an alkyne insertion reaction with decaborane from an mCPP-alkyne precursor. Subsequent deboronation reaction efficiently yields ionic mCPP compounds with a high fluorescence quantum yield (81%) in solution.
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