The microstructure of lignite and the seepage movement characteristics of ionic liquid solutions using 3D X-ray CT reconstruction

IF 4.6 2区 工程技术 Q2 ENGINEERING, CHEMICAL Powder Technology Pub Date : 2025-05-15 Epub Date: 2025-03-08 DOI:10.1016/j.powtec.2025.120884
Zijian Liu , Xi Chen , Jihai Chen , Shaocheng Ge , Qiucheng Deng , Haoru Li
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Abstract

For the difficulty of wetting coal seams through water injection, it is valuable to investigate the microscopic impact of ionic liquid solutions on the seepage process during water injection in coal seams. In this study, a 7 × 7 × 10 mm lignite sample was scanned using 3D X-ray CT technology. The coal structure was reconstructed using Avizo software, and subsequently, the seepage characteristics of water and ionic liquid solutions within the coal pore network were simulated using Comsol software in a region of 250 × 250 × 250 μm. The seepage simulation showed that when the pressure was constant, the pore and fracture network of the coal body exhibited significant anisotropy, and the water flow has different velocities in each direction. Specifically, the seepage velocity in the vertical direction (Z-axis) was 130 % and 11 % higher than that in the X- and Y-axes, respectively. By comparing the flow of water and ionic liquid solutions in the vertical direction (Z-axis), [BMIm][BF4] demonstrated the best seepage capability, and the low concentration range of 2 to 4 wt% was more conducive to the seepage movement of ionic liquids in coal. Moreover, simple pressurization could not effectively improve the seepage effect. Meanwhile, the wetting capability of ionic liquid solutions was not related to their seepage capability.

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三维x射线CT重建褐煤微观结构及离子液体溶液渗流运动特征
由于注水润湿煤层的难度较大,研究离子液体溶液对煤层注水渗流过程的微观影响具有重要意义。本研究采用三维x射线CT技术对7 × 7 × 10 mm褐煤样品进行扫描。利用Avizo软件对煤的结构进行重构,随后利用Comsol软件在250 × 250 × 250 μm范围内模拟煤孔隙网络中水和离子液体溶液的渗流特征。渗流模拟结果表明,当压力一定时,煤体孔隙和裂隙网络表现出明显的各向异性,水流在各个方向上具有不同的速度。其中,纵向(z轴)渗流速度比纵向(X轴)和纵向(y轴)分别高130%和11%。对比水与离子液体溶液在垂直方向(z轴)的流动情况,[BMIm][BF4]的渗流能力最好,2 ~ 4 wt%的低浓度范围更有利于离子液体在煤中的渗流运动。单纯的加压不能有效改善渗流效果。同时,离子液体溶液的润湿能力与其渗透能力无关。
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来源期刊
Powder Technology
Powder Technology 工程技术-工程:化工
CiteScore
9.90
自引率
15.40%
发文量
1047
审稿时长
46 days
期刊介绍: Powder Technology is an International Journal on the Science and Technology of Wet and Dry Particulate Systems. Powder Technology publishes papers on all aspects of the formation of particles and their characterisation and on the study of systems containing particulate solids. No limitation is imposed on the size of the particles, which may range from nanometre scale, as in pigments or aerosols, to that of mined or quarried materials. The following list of topics is not intended to be comprehensive, but rather to indicate typical subjects which fall within the scope of the journal's interests: Formation and synthesis of particles by precipitation and other methods. Modification of particles by agglomeration, coating, comminution and attrition. Characterisation of the size, shape, surface area, pore structure and strength of particles and agglomerates (including the origins and effects of inter particle forces). Packing, failure, flow and permeability of assemblies of particles. Particle-particle interactions and suspension rheology. Handling and processing operations such as slurry flow, fluidization, pneumatic conveying. Interactions between particles and their environment, including delivery of particulate products to the body. Applications of particle technology in production of pharmaceuticals, chemicals, foods, pigments, structural, and functional materials and in environmental and energy related matters. For materials-oriented contributions we are looking for articles revealing the effect of particle/powder characteristics (size, morphology and composition, in that order) on material performance or functionality and, ideally, comparison to any industrial standard.
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