Qing-Song Wei , Yi-Ming Di , Ming-Hua You , Hong-Ming Chen , Mei-Jin Lin
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引用次数: 0
Abstract
Photochromic materials, renowned for their reversible light-induced responses, have found widespread applications in areas such as optical storage, photosensitive devices and anti-counterfeiting technologies. Recently, metal-organic framework (MOF) radiochromic materials have attracted increasing attention due to their advantageous properties of good design flexibility, visualization capabilities, cost-effectiveness and rapid radiation response. These properties position MOFs as promising substitutes for traditional commercial radiation detection materials. In this review, we primarily discuss MOF radiation-induced chromic materials, which are driven by photoinduced electron transfer mechanisms resulting in radical generation, characterized by rapid radiation response and structural adaptability. Firstly, we explore the chromic mechanisms, performance evaluation parameters, and structural categories of MOF chromic materials. Subsequently, we discuss their multifunctional applications, followed by an analysis and summary of the modulation of their photoelectric response. Finally, we present our insights into the future development and structural modulation of MOF radiation-induced chromic materials, emphasizing their research significance and potential applications in radiation detection.
期刊介绍:
Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers.
The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.