Processable aqueous dispersions of graphene nanosheets

IF 38.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Nature nanotechnology Pub Date : 2008-01-27 DOI:10.1038/nnano.2007.451
Dan Li, Marc B. Müller, Scott Gilje, Richard B. Kaner, Gordon G. Wallace
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引用次数: 8174

Abstract

Graphene sheets offer extraordinary electronic, thermal and mechanical properties and are expected to find a variety of applications. A prerequisite for exploiting most proposed applications for graphene is the availability of processable graphene sheets in large quantities. The direct dispersion of hydrophobic graphite or graphene sheets in water without the assistance of dispersing agents has generally been considered to be an insurmountable challenge. Here we report that chemically converted graphene sheets obtained from graphite can readily form stable aqueous colloids through electrostatic stabilization. This discovery has enabled us to develop a facile approach to large-scale production of aqueous graphene dispersions without the need for polymeric or surfactant stabilizers. Our findings make it possible to process graphene materials using low-cost solution processing techniques, opening up enormous opportunities to use this unique carbon nanostructure for many technological applications.

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石墨烯纳米片的可加工水性分散体
石墨烯薄片具有非凡的电子、热和机械特性,有望被广泛应用。利用石墨烯的大多数拟议应用的前提条件是获得大量可加工的石墨烯薄片。疏水性石墨或石墨烯片在没有分散剂辅助的情况下直接分散在水中通常被认为是一项难以克服的挑战。在这里,我们报告了从石墨中获得的化学转化石墨烯片可以通过静电稳定作用轻松形成稳定的水性胶体。这一发现使我们能够开发出一种无需聚合物或表面活性剂稳定剂即可大规模生产水性石墨烯分散体的简便方法。我们的发现使使用低成本溶液加工技术加工石墨烯材料成为可能,为将这种独特的碳纳米结构用于多种技术应用带来了巨大的机遇。
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来源期刊
Nature nanotechnology
Nature nanotechnology 工程技术-材料科学:综合
CiteScore
59.70
自引率
0.80%
发文量
196
审稿时长
4-8 weeks
期刊介绍: Nature Nanotechnology is a prestigious journal that publishes high-quality papers in various areas of nanoscience and nanotechnology. The journal focuses on the design, characterization, and production of structures, devices, and systems that manipulate and control materials at atomic, molecular, and macromolecular scales. It encompasses both bottom-up and top-down approaches, as well as their combinations. Furthermore, Nature Nanotechnology fosters the exchange of ideas among researchers from diverse disciplines such as chemistry, physics, material science, biomedical research, engineering, and more. It promotes collaboration at the forefront of this multidisciplinary field. The journal covers a wide range of topics, from fundamental research in physics, chemistry, and biology, including computational work and simulations, to the development of innovative devices and technologies for various industrial sectors such as information technology, medicine, manufacturing, high-performance materials, energy, and environmental technologies. It includes coverage of organic, inorganic, and hybrid materials.
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