Analysis of antifreeze properties before and after their operation in engine

Oleg I. Telkov, Anastasia D. Kosmacheva, A. Khodyakov, S. Khlopkov, I. Danilov
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Abstract

The results of diagnostics of antifreeze indicators before and after their operation in an internal combustion engine are presented. The chosen direction of research is relevant, since it allows one to predict not only the change in the properties of antifreeze during its operation, but also to obtain evidence of the course of metal corrosion processes. The purpose of the study - to conduct control tests of antifreezes before and after their operation in an internal combustion engine, that ensures the maintenance of the power unit in good condition. The objects of study were fresh AGA Z-40-G12++ antifreeze (release of 2021; A-21) and coolant AGA Z-40-G12+ (release of 2012; AE-12) after its operation for several years. It is shown that the pH, density, viscosity, electrical conductivity of the coolant samples before and after its operation are different. It was found that the course of the dependences of electrical conductivity on temperature t for samples A-21 and AE-12 is the same. The dependence of on t is described by a polynomial (quadratic) model. It has been suggested that higher values of the AE-12 hydrogen index may indicate the occurrence of electrochemical corrosion of metals, which, in the process of contact with antifreeze, form short-circuited galvanic pairs. With the help of a complete factorial experiment, it was demonstrated that higher pH values of used antifreeze can be a reflection of the degradation of the properties of monoethylene glycol and the ongoing processes of metal corrosion.
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发动机使用前后防冻性能分析
介绍了内燃机防冻指示器运行前后的诊断结果。所选择的研究方向是相关的,因为它不仅允许人们预测防冻液在其运行过程中性能的变化,而且还可以获得金属腐蚀过程的证据。本研究的目的是对内燃机运行前后的防冻液进行控制试验,以确保动力单元处于良好状态。研究对象为新鲜AGA z -40- g12++防冻液(2021年发布;A-21)和冷却剂AGA Z-40-G12+(2012年发布;AE-12)运行数年后。结果表明,冷却液运行前后样品的pH值、密度、粘度、电导率均有差异。结果表明,A-21和AE-12的电导率随温度变化的过程是相同的。对t的依赖用多项式(二次)模型来描述。研究表明,AE-12氢指数较高可能表明金属在与防冻液接触过程中发生了电化学腐蚀,形成了短路的电偶。通过完全析因实验,证明了使用过的防冻液的较高pH值可以反映单乙二醇性能的降解和正在进行的金属腐蚀过程。
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