Archaeometric characterization of glass and a carnelian bead to study trade networks of two Swahili sites from the Ibo Island (Northern Mozambique)

IF 2.7 4区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS Boletin de la Sociedad Espanola de Ceramica y Vidrio Pub Date : 2023-09-01 DOI:10.1016/j.bsecv.2022.09.001
Manuel García-Heras , Fernando Agua , Hilario Madiquida , Víctor M. Fernández , María Ángeles Villegas , Marisa Ruiz-Gálvez
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Abstract

A representative set of glass from mostly Indo-Pacific type beads and other materials including a carnelian bead from two Swahili sites of the Ibo Island at Northern Mozambique has been archaeometrically characterized to get insights into its likely provenance within the framework of the Indian Ocean trade networks. Selected samples were examined and analyzed by using binocular magnifying glass, field emission scanning electron microscopy with energy dispersive X-ray microanalysis, visible spectrophotometry and X-ray diffraction. Up to four different types of glasses were identified according to its chemical composition: mineral-soda alumina glass from Western India, vegetal-soda alumina glass from Central Asia, a conventional soda-lime silicate glass coming probably from Europe and a lead silicate glass of the PbO-SiO2 binary system most likely from Venice. Red and yellow colours were obtained through colloidal chromophores: cuprite micro-crystals for red brick and lead stannate and/or lead antimoniate micro-crystals for yellow, while deep blue, greenish blue and yellowish colours were obtained through ionic chromophores. Either the carnelian bead or the different types of glass are imported materials resulting from Swahili trade networks of the Indian Ocean, since no evidence of glass production or recycling has been found in archaeological fieldwork.

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伊博岛(莫桑比克北部)两个斯瓦希里遗址的贸易网络研究:玻璃和玛瑙珠的考古特征
在莫桑比克北部伊博岛的两个斯瓦希里遗址中,一组具有代表性的玻璃主要由印度-太平洋类型的珠子和其他材料制成,其中包括一颗玛瑙珠,这些材料已被考古鉴定,以深入了解其在印度洋贸易网络框架内的可能来源。采用双筒放大镜、场发射扫描电镜-能量色散x射线显微分析、可见分光光度法和x射线衍射法对所选样品进行了检测和分析。根据其化学成分,鉴定出多达四种不同类型的玻璃:来自西印度的矿物-苏打氧化铝玻璃,来自中亚的植物-苏打氧化铝玻璃,可能来自欧洲的传统钠钙硅酸盐玻璃,以及最有可能来自威尼斯的PbO-SiO2二元体系的铅硅酸盐玻璃。通过胶体发色团可以得到红色和黄色:红砖用的是铜微晶体,黄色用的是锡酸铅和/或锑酸铅微晶体,而离子发色团可以得到深蓝色、绿蓝色和黄色。无论是玛瑙珠还是不同类型的玻璃都是从印度洋的斯瓦希里贸易网络进口的材料,因为在考古现场工作中没有发现玻璃生产或回收的证据。
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来源期刊
Boletin de la Sociedad Espanola de Ceramica y Vidrio
Boletin de la Sociedad Espanola de Ceramica y Vidrio 工程技术-材料科学:硅酸盐
CiteScore
5.50
自引率
2.90%
发文量
72
审稿时长
103 days
期刊介绍: The Journal of the Spanish Ceramic and Glass Society publishes scientific articles and communications describing original research and reviews relating to ceramic materials and glasses. The main interests are on novel generic science and technology establishing the relationships between synthesis, processing microstructure and properties of materials. Papers may deal with ceramics and glasses included in any of the conventional categories: structural, functional, traditional, composites and cultural heritage. The main objective of the Journal of the Spanish Ceramic and Glass Society is to sustain a high standard research quality by means of appropriate reviewing procedures.
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