Jing Dou , Yue Ma , Xiuxiu Niu , Wentao Zhou , Xueyuan Wei , Jie Dou , Zhenhua Cui , Qizhen Song , Tinglu Song , Huanping Zhou , Cheng Zhu , Yang Bai , Qi Chen
{"title":"Vacancy healing for stable perovskite solar cells via bifunctional potassium tartrate","authors":"Jing Dou , Yue Ma , Xiuxiu Niu , Wentao Zhou , Xueyuan Wei , Jie Dou , Zhenhua Cui , Qizhen Song , Tinglu Song , Huanping Zhou , Cheng Zhu , Yang Bai , Qi Chen","doi":"10.1016/j.jechem.2023.09.008","DOIUrl":null,"url":null,"abstract":"<div><p>Perovskite solar cell has gained widespread attention as a promising technology for renewable energy. However, their commercial viability has been hampered by their long-term stability and potential Pb leakage. Herein, we demonstrate a bifunctional passivator of the potassium tartrate (PT) to address both challenges. PT minimizes the Pb leakage in perovskites and also heals cationic vacancy defects, resulting in improved device performance and stability. Benefiting from PT modification, the power conversion efficiency (PCE) is improved to 23.26% and the Pb leakage in unencapsulated films is significantly reduced to 9.79 ppm. Furthermore, the corresponding device exhibits no significant decay in PCE after tracking at the maximum power point (MPP) for 2000 h under illumination (LED source, 100 mW cm<sup>−2</sup>).</p></div>","PeriodicalId":67498,"journal":{"name":"能源化学","volume":"88 ","pages":"Pages 64-70"},"PeriodicalIF":14.0000,"publicationDate":"2023-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"能源化学","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2095495623005144","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0
Abstract
Perovskite solar cell has gained widespread attention as a promising technology for renewable energy. However, their commercial viability has been hampered by their long-term stability and potential Pb leakage. Herein, we demonstrate a bifunctional passivator of the potassium tartrate (PT) to address both challenges. PT minimizes the Pb leakage in perovskites and also heals cationic vacancy defects, resulting in improved device performance and stability. Benefiting from PT modification, the power conversion efficiency (PCE) is improved to 23.26% and the Pb leakage in unencapsulated films is significantly reduced to 9.79 ppm. Furthermore, the corresponding device exhibits no significant decay in PCE after tracking at the maximum power point (MPP) for 2000 h under illumination (LED source, 100 mW cm−2).
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