{"title":"Acid hydrolysis of tetrahydropyranyl glycosides: Effects of 2-methylation and 3-hydroxylation on rate of hydrolysis","authors":"Robert V. Petersen","doi":"10.1002/jps.3030491204","DOIUrl":null,"url":null,"abstract":"<div><p>A series of methyl glycosides (acetals and ketals) analogous to aldopyranosides, ketopyranosides, and their 3-hydroxy analogs (tetrahydropyran, 2-methyl-tetrahydropyran, and 3-hydroxyl derivatives of these compounds) were synthesized, subjected to acids of various concentrations, and their rates of hydrolysis determined spectrophotometrically.</p></div>","PeriodicalId":100839,"journal":{"name":"Journal of the American Pharmaceutical Association (Scientific ed.)","volume":"49 12","pages":"Pages 750-755"},"PeriodicalIF":0.0000,"publicationDate":"1960-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/jps.3030491204","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the American Pharmaceutical Association (Scientific ed.)","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0095955315300044","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
Abstract
A series of methyl glycosides (acetals and ketals) analogous to aldopyranosides, ketopyranosides, and their 3-hydroxy analogs (tetrahydropyran, 2-methyl-tetrahydropyran, and 3-hydroxyl derivatives of these compounds) were synthesized, subjected to acids of various concentrations, and their rates of hydrolysis determined spectrophotometrically.
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