Improvement of AlGaAs solar cell grown on Si substrate

T. Soga, M. Yang, Y. Azuma, H. Uchida, T. Jimbo, M. Umeno
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Abstract

The improvement of Al/sub 0.1/Ga/sub 0.9/As solar cell grown on Si substrate by metalorganic chemical vapor deposition has been described in this paper. The conversion efficiency as high as 12.9% has been obtained by employing the high growth temperature, the high annealing temperature during the growth, the long hold time at the annealing temperature and graded band emitter layer. A novel technique to reduce the stress of GaAs grown on Si is demonstrated. GaAs was grown on Si with GaSb intermediate layer, followed by the laser pulse irradiation (wavelength is 1.064 mm, the pulse width is 140 ps and pulse energy is 40 mJ/pulse). The stress of GaAs on Si with 10 laser shots is one-fourth of that before laser irradiation. The stress-relaxed AlGaAs solar cell structure on Si is proposed.
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硅衬底生长AlGaAs太阳能电池的改进
本文介绍了金属有机化学气相沉积法在硅衬底上生长Al/sub 0.1/Ga/sub 0.9/As太阳电池的改进。采用高生长温度、生长过程中较高的退火温度、退火温度下较长的保温时间和渐变带发射极层,可获得高达12.9%的转换效率。提出了一种新的方法来降低生长在硅上的砷化镓的应力。采用GaSb中间层在Si表面生长GaAs,激光脉冲照射(波长1.064 mm,脉宽140 ps,脉冲能量40 mJ/脉冲)。经过10次激光照射后,GaAs在Si上的应力是激光照射前的1 / 4。提出了应力松弛的硅基AlGaAs太阳能电池结构。
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