Extremely non-porous ultra-low-k SiOCH (k=2.3) with sufficient modulus (>10 GPa), high Cu diffusion barrier and high tolerance for integration process formed by large-radius neutral-beam enhanced CVD

Y. Kikuchi, A. Wada, S. Samukawa
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引用次数: 1

Abstract

We developed a practical large-radius neutral beam enhanced CVD with a dimethoxy tetramethy ldisiloxane (DMOTMDS) to form low-k SiOCH film on 8-inch Si wafers. We fabricated extremely non-porous film with an ultra-low k-value of 2.3 and a sufficient modulus (>10 GPa). This particular film did not show any damage from the oxygen plasma and acid or alkali solutions used in the fabrication process. Furthermore, the dense film almost completely resisted Cu diffusion into the film during thermal annealing.
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极无孔超低k SiOCH (k=2.3),具有足够的模量(>10 GPa),高Cu扩散势垒,对大半径中性束增强CVD形成的集成过程具有高耐受性
我们开发了一种实用的大半径中性束增强CVD,使用二甲氧基四甲基硅氧烷(DMOTMDS)在8英寸硅晶片上形成低k SiOCH薄膜。我们制备了具有超低k值2.3和足够模量(>10 GPa)的极无孔薄膜。这种特殊的薄膜在制造过程中没有显示出氧等离子体和酸或碱溶液的任何损坏。此外,在热处理过程中,致密的薄膜几乎完全阻止了Cu向薄膜中的扩散。
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