Progress of Lead-Free Halide Perovskite X-ray Detectors

Hainan Zhang, Guanhua Dun, Y. Qiao, D. Xie, T. Ren
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Abstract

Lead halide perovskite for radiation detection still faces significant challenges despite its exciting progress. The main issues which hinder further development are the toxicity problem of lead and the intrinsic instability for volatile organic parts in lead-based perovskites. Therefore, searching for low-toxic and intrinsically stable perovskite materials have drawn a great attention from the public. In this review, lead-free perovskites are divided into two types: double perovskites type as A2MIMIIX6 and low-dimensional perovskites type as A3W2X9. The synthesis methods of these lead-free perovskites are discussed and the performance on X-ray detection are accordingly summarized. Moreover, a brief outlook on the future development of lead-free perovskites in radiation detection is proposed.
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无铅卤化物钙钛矿x射线探测器的研究进展
尽管卤化铅钙钛矿在辐射探测方面取得了令人振奋的进展,但仍面临着重大挑战。阻碍铅基钙钛矿进一步发展的主要问题是铅的毒性问题和铅基钙钛矿中挥发性有机组分的固有不稳定性。因此,寻找低毒、本质稳定的钙钛矿材料引起了公众的极大关注。本文将无铅钙钛矿分为两种类型:双钙钛矿型A2MIMIIX6和低维钙钛矿型A3W2X9。讨论了这些无铅钙钛矿的合成方法,并对其x射线检测性能进行了总结。最后,对无铅钙钛矿在辐射检测中的应用前景进行了展望。
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