Effects of Nanocrack Behavior on Radiation-Induced, Elastic Modulus Changes in Nuclear Graphites

J. Spicer
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Abstract

The elastic responses of nuclear graphites depend not only on the graphitic content itself but are largely dictated by the microstructural constitution of the material. The types of raw materials combined with the manufacturing processes used to produce the graphite yield the microstructural content which primarily includes graphite filler, graphitized pitch binder, and voids/defects that typically occupy approximately 20% of the volume. Among these microstructural components, porosity, microcracking (considered to be part of voids/defects) and intracrystallite nanocracking (Mrozowski cracks) heavily influence the overall properties of the material including the elastic moduli. Models describing the elastic moduli of porous, polycrystalline graphite materials have been developed to interpret experimental determinations of Young's modulus and shear modulus in oxidized graphites, and these include the effects of nano/microcracks. This work will demonstrate the role that the effects of neutron irradiation on Mrozowski cracks could have on the phenomenon of turnaround in nuclear graphites and will present directions to be pursued to account for microstructure-related effects that generally occur as a result of neutron irradiation.
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纳米裂纹行为对辐射诱导核石墨弹性模量变化的影响
核石墨的弹性响应不仅取决于石墨本身的含量,而且在很大程度上取决于材料的微观结构构成。原材料类型与用于生产石墨的制造工艺相结合,产生微观结构含量,主要包括石墨填料、石墨化沥青粘合剂和通常占体积约20%的空隙/缺陷。在这些微观结构成分中,孔隙率、微裂纹(被认为是空洞/缺陷的一部分)和晶内纳米裂纹(Mrozowski裂纹)严重影响材料的整体性能,包括弹性模量。描述多孔多晶石墨材料弹性模量的模型已经被开发出来,用于解释氧化石墨中杨氏模量和剪切模量的实验测定,其中包括纳米/微裂纹的影响。这项工作将证明中子辐照对Mrozowski裂纹的影响可能对核石墨的旋转现象产生的作用,并将提出需要追求的方向,以解释通常由于中子辐照而发生的与微结构相关的影响。
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