A new analytical method based on Co-Mo nanoparticles supported by carbon nanotubes for removal of mercury vapor from the air by the amalgamation of solid-phase air removal

Danial Soleymani-Ghoozhdi, Rouhollah Parvari, Yunes Jahani, Morteza Mehdipour-Raboury, A. Faghihi-Zarandi
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引用次数: 1

Abstract

Heavy metals are a major cause of environmental pollution, and mercury is a well-known toxicant that is extremely harmful to the environment and human health. In this study, new carbon nanotubes coated with cobalt and molybdenum nanoparticles (Co-Mo/MWCNT) were used for Hg0 removal from the air by the amalgamation of solid-phase air removal method (ASPAR). In the bench-scale setup, the mercury vapor in air composition was produced by the mercury vapor generation system (HgGS) and restored in a polyethylene airbag . In optimized conditions, the mercury vapor in the airbag passed through Co-Mo/MWCNT and was absorbed on it. Then, the mercury was completely desorbed from Co-Mo/MWCNT by increasing temperature up to 220 °C and online determined by cold vapor atomic absorption spectrometry (CV-AAS). The recovery and capacity of Co-Mo/MWCNT were obtained at 98% and 191.3 mg g-1, respectively. The Repeatability of the method was 32 times. The mercury vapors absorbed on Co-Mo/MWCNT adsorbent could be maintained at 7 days at the refrigerator temperature. The Co-Mo/MWCNT as a sorbent has many advantages such as; high capacity, renewable, good repeatability and chemical adsorption (amalgamation) of mercury removal from the air. The method was successfully validated by MCA and spiking of real samples.
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基于碳纳米管负载的Co-Mo纳米颗粒,采用固相空气混合法去除空气中的汞蒸汽
重金属是造成环境污染的主要原因,而汞是一种众所周知的对环境和人体健康极为有害的有毒物质。在本研究中,采用复合固相空气去除法(ASPAR),采用包覆钴和钼纳米颗粒的新型碳纳米管(Co-Mo/MWCNT)去除空气中的Hg0。在实验装置中,空气成分中的汞蒸汽由汞蒸汽产生系统(HgGS)产生,并恢复到聚乙烯安全气囊中。在优化条件下,安全气囊中的汞蒸气通过Co-Mo/MWCNT并被其吸收。然后,将温度升高至220℃,通过冷蒸汽原子吸收光谱法(CV-AAS)在线测定Co-Mo/MWCNT中的汞完全解吸。Co-Mo/MWCNT的回收率为98%,容量为191.3 mg g-1。方法重复性为32次。在冰箱温度下,Co-Mo/MWCNT吸附剂吸附的汞蒸气可保持7天。Co-Mo/MWCNT作为吸附剂具有许多优点,如;高容量,可再生,重复性好,化学吸附(汞齐)去除空气中的汞。通过实际样品的MCA和峰值分析验证了该方法的有效性。
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