OBTAINING HUMATE-CONTAINING NEW COMPOSITE PRODUCTS

U. Dzhusi̇pbekov, G. Nurgalieva, Z. Bayakhmetova, A. K. Shakirova
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Abstract

The influence of various factors on the process of interaction in the systems "sodium humate-mixture of phosphoric and nitric acids" and "phosphorite-mixture of acids-sodium humate" has been investigated. The influence of the ratios of the initial components, the amount of sodium humate introduced, the rate of the acid reagent, the temperature and duration of the reaction on the interaction process in the systems under study was studied, and the optimal process conditions were determined. The methods of chemical and physicochemical analysis revealed that as a result of interaction in the studied heterogeneous systems, ammonium humate, sodium acid phosphates, as well as sodium and ammonium nitrates are formed. Based on the studies carried out, it was found that the introduction of sodium humate prevents the inhibition of the decomposition of phosphate raw materials and the retrogradation of P2O5, i.e. the sparingly soluble calcium hydrogen phosphate formed as a result of the interaction of the initial components under the influence of sodium humate transforms into a readily soluble dihydrogen phosphate. A basic technological scheme for obtaining new types of humate-containing composite products has been developed. A basic technological scheme for obtaining new types of humate-containing products has been developed, which allows obtaining two types of products: fertilizers and compositions. When sodium humate interacts with an acidic reagent, the finished product is a humate composition, and if phosphorite is added to the system, a humate-phosphate fertilizer. The resulting products have a high content of P2O5, nitrogen and humic substances.
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获得含腐植酸的新型复合产品
研究了各种因素对“腐植酸钠-磷酸-硝酸混合物”体系和“磷酸-酸-腐植酸钠”体系相互作用过程的影响。研究了初始组分的配比、腐植酸钠的加入量、酸试剂的速率、反应温度和反应时间等因素对反应过程的影响,确定了最佳工艺条件。化学和物理化学分析方法表明,在研究的非均相体系中,由于相互作用,形成了腐植酸铵、酸性磷酸钠以及硝酸钠和硝酸铵。通过研究发现,腐植酸钠的引入抑制了磷酸盐原料分解和P2O5的退化,即初始组分在腐植酸钠的影响下相互作用形成的难溶性磷酸氢钙转化为易溶的磷酸二氢。提出了制备新型含腐植酸复合材料的基本工艺方案。已经开发了一种获得新型含腐植酸产品的基本技术方案,可以获得两种产品:肥料和组合物。当腐植酸钠与酸性试剂相互作用时,最终产物是腐植酸组成物,如果在系统中添加磷矿,则是腐植酸-磷肥。所得产物P2O5、氮和腐殖质含量高。
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