Contamination Status of Polycyclic Aromatic Hydrocarbons (PAH s) In Atmospheric Particulate Matter PM2.5 Samples of a Semi-Residential Area of Dhaka, Bangladesh
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引用次数: 1
Abstract
This study deals with the determination of the polycyclic aromatic hydrocarbons (PAHs) in the atmospheric particulate matters (PM 2.5 ) at a semi residential site of Gazipur, Dhaka, Bangladesh. Source identification and possible human health impact of polycyclic aromatic hydrocarbon was evaluated as well. A total of 20 samples were collected in six weeks period of time. Polycyclic Aromatic Hydrocarbons (PAH’s) were determined using gas chromatography-mass spectrometry. The average concentration of Anthracene, Phenanthrene, Pyrene, Chrysene, Benzo (a) anthracene, Benzo(a)pyrene, perylene were found to be 0.309, 0.159, 0.227, 2.120, 1.954, 2.269 and 3.373µgm -3 respectively. Two-way ANOVA test revealed that the concentration of different PAHs species (F cal > F crit ) are significantly different from each other at a 95% confidence level. The main contributory sources for PAHs were found gasoline exhaust, diesel exhaust, wood burning and brick kilns. The result revealed that these compounds are present in a higher level in the atmosphere when compared with the value of other countries in the world. Concentration of highly carcinogenic Benzo(a) pyrene was in a range where carcinogenic effect is an immediate threat in case of long-time exposure and hence regular monitoring is suggested.
本研究涉及在孟加拉国达卡加齐浦尔的半居住区大气颗粒物(PM 2.5)中多环芳烃(PAHs)的测定。并对多环芳烃的来源鉴定及可能对人体健康的影响进行了评价。在6周的时间内共采集20份样本。采用气相色谱-质谱联用技术对多环芳烃(PAH)进行了测定。蒽、菲、芘、芘、苯并(a)蒽、苯并(a)芘、苝的平均浓度分别为0.309、0.159、0.227、2.120、1.954、2.269和3.373µgm -3。双因素方差分析显示,在95%的置信水平上,不同多环芳烃种类的浓度(F cal > F crit)差异显著。多环芳烃的主要来源是汽油废气、柴油废气、木材燃烧和砖窑。结果显示,与世界其他国家相比,这些化合物在大气中的含量更高。高致癌性苯并(a)芘的浓度处于长期接触会产生直接致癌威胁的范围内,因此建议定期监测。