Influence of the Ga content on the optical and electrical properties of CuIn1−xGaxSe2 thin-film solar cells

Zhenhao Zhang, W. Witte, O. Kiowski, U. Lemmer, M. Powalla, Hendrik Holscher
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引用次数: 3

Abstract

Thin-film solar cells that are based on Cu(In,Ga)Se2 (CIGS) absorbers with Ga/(Ga+In)-ratios from 0 to 1 are fabricated, and their optical and electrical properties are investigated by macroscopic (current density-voltage, external quantum efficiency) and microscopic (Kelvin probe force microscopy on untreated cross sections of solar cells) measurements. Combining all results, the diffusion voltages of individual solar cells are deduced and compared with the directly measured open-circuit voltages. An increasing splitoff between the diffusion voltage and the opencircuit voltage is observed forGa addition,which indicates a higher recombination rate of photogenerated charge carriers in solar cells with higher Ga content.
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Ga含量对CuIn1−xGaxSe2薄膜太阳能电池光电性能的影响
制备了Ga/(Ga+In)比为0 ~ 1的Cu(In,Ga)Se2 (CIGS)吸收体薄膜太阳能电池,并通过宏观(电流密度-电压、外量子效率)和微观(开尔文探针力显微镜在未经处理的太阳能电池截面上)测量研究了其光学和电学性能。结合所有结果,推导出单个太阳能电池的扩散电压,并与直接测量的开路电压进行了比较。添加Ga时,扩散电压和开环电压之间的分裂增大,表明在Ga含量高的太阳能电池中,光生载流子的复合率更高。
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