Characterization of ceria powders as a continuous search for new rare-earth based materials for radiation dosimetry

S. Santos, O. Rodrigues, L. Campos
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Abstract

Ceria (CeO2) belongs to rare-earth series and due to its profitable properties, presents a wide commercial use such as catalysis, energy, biological, biomedical, and pharmaceutical. The features of the starting materials in the form of free powders influence notably the processing, formation, as well as characteristics of the final structures\bodies obtained by colloidal processing. This study aims to characterize CeO2 powders. The results obtained are worthwhile data to advance toward new rare-earth based materials for radiation dosimetry. CeO2 powders were evaluated by the following techniques: PCS, SEM, XRD, FT-IR, EPR, IPC, and pycnometric density (ρ). The stability of particles in aqueous solvent was evaluated by zeta potential (ζ) determination. CeO2 powders exhibited cubic C-type form, Fm-3m space group, a mean particle size (d50) of 19.3nm, and a pycnometric density (ρ) of 7.01g.cm-3. Based on the results of zeta potential determination, CeO2 powders exhibited high stability at pH 6.4 with ζ-value of |34.0|mV. The evaluation of CeO2 powders was reported. The results presented and discussed in this study contribute to advance in the search of new rare-earth based materials for radiation dosimetry.
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表征铈粉作为辐射剂量学新稀土基材料的不断探索
铈(CeO2)属于稀土系列,由于其有利的性质,在催化、能源、生物、生物医学和制药等领域具有广泛的商业用途。以游离粉末形式存在的起始材料的特征显著地影响通过胶体加工获得的最终结构体的加工、形成和特性。本研究旨在对CeO2粉末进行表征。所得结果为开发新型稀土基辐射剂量学材料提供了有价值的数据。采用PCS、SEM、XRD、FT-IR、EPR、IPC和密度(ρ)等技术对CeO2粉末进行了表征。采用ζ电位(ζ)测定法评价颗粒在水溶液中的稳定性。CeO2粉末呈立方c型,空间群为Fm-3m,平均粒径(d50)为19.3nm,比密度(ρ)为7.01g.cm-3。zeta电位测定结果表明,CeO2粉体在pH 6.4时表现出较高的稳定性,ζ值为34.0|mV。报道了对CeO2粉末的评价。本研究提出和讨论的结果有助于推动寻找新的稀土基辐射剂量学材料。
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来源期刊
Current Materials Science
Current Materials Science Materials Science-Materials Science (all)
CiteScore
0.80
自引率
0.00%
发文量
38
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