Preparation of chitosan films plasticized by lauric and maleic acids

S. Mutasher, H. Al-Lami
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Abstract

The energy crisis and environmental concerns have increased interest in natural polymers, and the bio-sourced materials field is experiencing rapid growth. A useful alternative to conventional plastic packaging manufactured from fossil fuels is packaging constructed of biodegradable polymers. Consideration has been given to the instrumental methods for examining modifications to the chemical composition and characteristics of modified chitosan. The molecular weight and the kind of plasticizer present in these materials are the two primary variables influencing their usability and performance. This study set out to physically blend chitosan with two different acids, lauric and maleic, to enhance chitosan cast films' physical and mechanical properties. Different plasticizer ratios appeared to have little effect on the various properties of the chitosan cast films. Examining the obtained films by FTIR implies that chitosan's native structure was unchanged. The films prepared had more flexibility and better solubility than those made with un-plasticized chitosan. It was evident from an analysis of the mechanical properties of the films that both acid plasticizers enhanced the mechanical properties of the chitosan.
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月桂酸和马来酸增塑壳聚糖膜的制备
能源危机和环境问题增加了人们对天然聚合物的兴趣,生物源材料领域正在经历快速增长。由生物可降解聚合物构成的包装,是替代由化石燃料制造的传统塑料包装的一种有用的选择。讨论了检测改性壳聚糖的化学组成和特性的仪器方法。这些材料中存在的分子量和增塑剂的种类是影响其可用性和性能的两个主要变量。本研究将壳聚糖与月桂酸和马来酸进行物理共混,以提高壳聚糖铸膜的物理力学性能。不同增塑剂配比对壳聚糖铸膜的各项性能影响不大。用FTIR对制备的膜进行检测,表明壳聚糖的天然结构没有改变。制备的膜比未增塑的壳聚糖具有更大的柔韧性和更好的溶解度。对壳聚糖薄膜力学性能的分析表明,两种酸性增塑剂均能提高壳聚糖薄膜的力学性能。
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