INFLUENCE OF THE NATURE OF THE MODIFIER ON THE SORPTION PROPERTIES OF SHANKANAI ZEOLITE

R. Kaiynbayeva, N.N. Kojabekova, G. Sultanbayeva, А.А. Аgatayeva, R. Chernyakova, U. Jussipbekov
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Abstract

Sorbents modified with hydrochloric acid and chitosan based on the Shankanai bridge formation zeolite were obtained, and the effect of drying temperature on the sorption properties of sorbents was studied. It was found that 25 °C is the optimal temperature for obtaining acid-modified zeolite. A chitosan-modified sorbent with good sorption characteristics can be obtained at 25 °C with cation-exchange (COE 68.05 mg-eq/g) and 70°C with anion-exchange (SEC 70.16 mg-eq/g) properties. Physicochemical analysis of modified zeolites showed an increase in the size of voids and channels on the surface of acid-modified zeolite, and when modified with chitosan, the latter is crosslinked with the surface of natural zeolite.
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改性剂性质对山卡奈沸石吸附性能的影响
以山卡内桥型分子筛为基础,制备了盐酸和壳聚糖改性的吸附剂,并研究了干燥温度对吸附剂吸附性能的影响。结果表明,25℃是制备酸改性沸石的最佳温度。壳聚糖改性吸附剂在25℃的阳离子交换性能(COE为68.05 mg-eq/g)和70℃的阴离子交换性能(SEC为70.16 mg-eq/g)下具有良好的吸附特性。对改性沸石的理化分析表明,酸改性沸石表面的孔洞和孔道尺寸增大,壳聚糖改性后,后者与天然沸石表面发生交联。
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