Effects of Composition on Photoluminescence Properties of Organometal Halide Perovskites Quantum Dots

Pengfei Wang, Jinhua Li, Yue Wang, Ke Feng, X. Chu, Yingjiao Zhai, P. Zou, W. Fang, F. Jin
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Abstract

Organometal halide perovskites material have recently emerged have shown great potential in photovoltaic and light emitting application. As an emerging nanomaterial, perovskite quantum dots have high fluorescence quantum yield, narrow half-peak width and fluorescence wavelength which can cover the whole visible region. Organometal halide perovskites quantum dots are one of the typical quantum dots, quantum dots have large exciton binding energy, quantum confinement effect, and therefore has a high fluorescence quantum yield. Because of its robust quantum size effect, regulate the size of quantum dots can achieve its performance adjustment. In this paper, the size of the perovskite quantum dots was adjusted by changing the composition and ratio of the halogen, thereby changing the forbidden bandwidth of the quantum dots to achieve the control of the emission wavelength. In this way, we study the optical properties of organometal halide perovskites quantum dots and understanding the quantum size effects of perovskite quantum dots and the ability to turn their size.
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组成对有机金属卤化物钙钛矿量子点光致发光性能的影响
近年来出现的有机金属卤化物钙钛矿材料在光伏和发光方面显示出巨大的应用潜力。钙钛矿量子点作为一种新兴的纳米材料,具有荧光量子产率高、半峰宽度窄、荧光波长可覆盖整个可见光区域等特点。有机金属卤化物钙钛矿量子点是典型的量子点之一,量子点具有较大的激子结合能、量子约束效应,因此具有较高的荧光量子产率。由于量子点具有强大的量子尺寸效应,调节量子点的尺寸可以实现其性能的调节。本文通过改变卤素的组成和比例来调节钙钛矿量子点的尺寸,从而改变量子点的禁带带宽,实现对发射波长的控制。通过这种方式,我们研究了有机金属卤化物钙钛矿量子点的光学性质,了解了钙钛矿量子点的量子尺寸效应和改变其尺寸的能力。
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