Influence of Fluence and Pulse Number on Laser‐Cleaning of Atmospheric Pressure Plasma Jet Etched Optical Glasses

Robert Heinke, Thomas Arnold, M. Ehrhardt, P. Lorenz, K. Zimmer
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Abstract

The use of beam‐based technologies to process optical elements with nano‐scale precision enables the fabrication of freeform surfaces. Especially, atmospheric pressure plasma jets (APPJ) have desirable properties such as atmospheric pressure machining, dry processing and direct writing capabilities. However, the presence of metal oxides in optical glasses leads to the formation of non‐volatile reaction products during APPJ etching with fluorine‐containing gas mixtures, forming a residual layer that increases surface roughness and alters etching behavior. To prevent the formation of the residual layer the APPJ process is combined with laser‐cleaning. For a possible future in‐situ cleaning of the residual layer during the plasma process, laser parameter ranges need to be found to remove the residual layer without damaging the glass surface. Therefore, planar etchings are performed by APPJ on N‐BK7 and Zerodur and the etched planes are subsequently laser‐irradiated with varying pulse numbers and fluences. The processed samples are then examined by SEM. For both N‐BK7 and Zerodur, a parameter range is identified that results in clean surfaces. The best machining results are achieved with 2 ‐ 16 pulses and laser fluences of 0.6 ‐ 1.2 J cm‐2 for N‐BK7 and 0.56 ‐ 0.7 J cm‐2 for Zerodur.This article is protected by copyright. All rights reserved.
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通量和脉冲数对常压等离子体射流蚀刻光学玻璃激光清洗的影响
利用基于光束的技术以纳米级精度加工光学元件,可以制造自由曲面。特别是常压等离子体射流(APPJ)具有常压加工、干加工和直接写入等性能。然而,光学玻璃中金属氧化物的存在导致在含氟气体混合物的APPJ蚀刻过程中形成非挥发性反应产物,形成残留层,增加表面粗糙度并改变蚀刻行为。为了防止残余层的形成,APPJ工艺与激光清洗相结合。为了将来可能在等离子体过程中对残余层进行原位清洗,需要找到在不损坏玻璃表面的情况下去除残余层的激光参数范围。因此,APPJ在N - BK7和Zerodur上进行平面蚀刻,然后用不同的脉冲数和影响对蚀刻平面进行激光照射。然后用扫描电镜检查处理后的样品。对于N‐BK7和Zerodur,确定了一个参数范围,导致表面清洁。N - BK7和Zerodur分别在2 - 16个脉冲和0.6 - 1.2 J cm - 2的激光影响下获得了最佳的加工效果。这篇文章受版权保护。版权所有。
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