Effects of Zn (II) on the Optical Properties of CdTe Quantum Dots and Their Photoluminescence Response to Lead Ion

N. Nhan, Vu Anh Duc, Mai Xuân Dũng, Hoàng Quang Bắc
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Abstract

Water-soluble CdTe quantum dots (QDs) have been utilized as photoluminescence probes for the detection of metal ions such as Pb2+, Hg2+, Cd2+, etc. We initially developed highly photoluminescence (PL) Zn-doped CdTe for toxic ions detection. A study on the changes of optical properties of Zn-doped CdTe and CdTe QDs when exposed to Pb2+ suggested that Pb2+ could act as a surface passivating agent to reduce Te2- dangling bonds while Zn2+ dopant stabilizes the QDs surface against ambient oxidation. The results demonstrated herein provide useful  understandings of the interactions between water-soluble QDs and metal ions. These results suggest further applications of QDs in sensing metal ions.
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Zn (II)对CdTe量子点光学性质的影响及其对铅离子的光致发光响应
水溶性CdTe量子点(QDs)已被用作光致发光探针,用于探测Pb2+、Hg2+、Cd2+等金属离子。我们最初开发了高光致发光(PL)锌掺杂CdTe用于有毒离子检测。研究了掺杂锌的CdTe和CdTe量子点在Pb2+作用下光学性质的变化,表明Pb2+可以作为表面钝化剂减少Te2-悬空键,而掺杂Zn2+则可以稳定量子点的表面,防止环境氧化。本文所证明的结果为水溶性量子点与金属离子之间的相互作用提供了有用的理解。这些结果为量子点在传感金属离子方面的进一步应用提供了依据。
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