Optical characterization of CuInSe/sub 2/ grown by molecular beam epitaxy

S. Niki, Y. Makita, A. Yamada, H. Shibata, P. Fons, A. Obara, T. Kurafuji, S. Chichibu, N. Nakanishi
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引用次数: 0

Abstract

CuInSe/sub 2/ epitaxial films with near stoichiometric compositions have been grown on GaAs (001) by molecular beam epitaxy, and radiative recombination processes in these films have been characterized by means of low temperature photoluminescence (PL) spectroscopy. Temperature dependent PL measurements on such epitaxial films have made possible the identification of conduction band to acceptor and donor-acceptor pair transitions. Well-defined emission lines were present near the bandgap, and the emissions at 1.0386 eV and at 1.0311 eV were found to be due to the ground-state free exciton and the excitons bound to neutral acceptors, respectively. The bandgap of CuInSe/sub 2/ is also determined to be E/sub g/=1.0462 eV at 2 K.
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分子束外延生长CuInSe/ sub2 /的光学特性
采用分子束外延的方法在GaAs(001)上生长了具有接近化学计量组成的CuInSe/sub 2/外延薄膜,并利用低温光致发光(PL)光谱对薄膜中的辐射复合过程进行了表征。在这种外延薄膜上的温度相关PL测量使得识别传导带到受体和供体-受体对的转变成为可能。在带隙附近有清晰的发射线,1.0386 eV和1.0311 eV的发射分别是由基态自由激子和中性受体结合的激子引起的。CuInSe/sub 2/的带隙也确定为E/sub g/=1.0462 eV。
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