Influence of operating time on the corrosion in single-phase and two-phase media

Valeriy Ivanovich Baranenko, O. M. Gulina, N. L. Salnikov
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Abstract

Modern foreign computer codes predict a linear growth in the pipeline wall thinning with time due to the process of flow-accelerated corrosion (FAC), i.e. erosion-corrosion wear (ECW). Linear time-thinning dependence and corrosion rate constancy are not however typical of the NPP piping operating conditions. And the associated excessive conservatism of the residual life estimates leads to increased economic costs of repeated inspections. In domestic software tools, EKI-02 and EKI-03, the influence of operating time are taken into account by introducing the respective coefficient into the Chexal-Horowitz model based on the yield of corrosion products into the coolant. The ECW intensity can be however reduced through improvements in operating conditions, preventive measures, improvements in water chemistry, etc., and the use of the dependences once obtained may turn out to be too conservative. Based on a large number of repeated measurements as well as on data from corrosion testers, it has been shown that the influence of time can be described by the function of a particular form, the coefficients of which differ for different units and component and subsystem types. This makes it possible to determine the ‘aging function’ based on inspection data, and then use it in a targeted way for particular components. It has been shown that such estimates are much less conservative.
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操作时间对单相和两相介质腐蚀的影响
现代国外计算机代码预测,由于流动加速腐蚀(FAC)过程,即侵蚀-腐蚀磨损(ECW),管道壁随时间变薄呈线性增长。然而,线性时间稀释依赖性和腐蚀速率常数并不是核电厂管道运行条件的典型特征。与此相关的剩余寿命估计的过度保守性导致重复检查的经济成本增加。在国内的软件工具EKI-02和EKI-03中,根据腐蚀产物进入冷却剂的量,在Chexal-Horowitz模型中引入了相应的系数,考虑了操作时间的影响。然而,可以通过改善操作条件、预防措施、改善水化学等措施来降低ECW强度,并且一旦获得依赖性的使用可能会变得过于保守。根据大量的重复测量和腐蚀试验数据,时间的影响可以用一种特定形式的函数来描述,其系数因单元、部件和子系统类型的不同而不同。这使得根据检测数据确定“老化函数”成为可能,然后针对特定部件有针对性地使用它。事实证明,这样的估计远没有那么保守。
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