Evaluation of photodegradation efficiency on semiconductor immobilized clay photocatalyst by using probit model approximation

Jaka Nugraha , Is Fatimah
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引用次数: 6

Abstract

Photodegradation process and mechanism is a relative new and eco-friendly process to recycle and reuse of water. Some investigation concerned with effort to increase photocatalyst activity by immobilizing semiconductor oxide such as ZnO in clay as solid support. It was related to that photodegradation was directed by adsorption mechanism. However sometimes the activity of a photocatalyst is not linearly correlated with adsorption mechanism. In this research evaluation on photoactivity of ZnO-hectorite (ZnO/CTMA/Hectorite) and TiO2-montmorillonite based material using statistical approximation compared to the linear model is studied. The model is evaluated for photodegradation of phenol solution. Some beneficial results of the probit model are (i) the guarantee of activity prediction value in the range of 0–100% (ii) interaction of adsorption and photodegradation mechanism is well described.

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用probit模型近似评价半导体固定化粘土光催化剂的光降解效率
光降解工艺和机理是一种较新的、生态友好的水循环再利用工艺。一些研究是通过将半导体氧化物如ZnO固定在粘土中作为固体载体来提高光催化剂的活性。这与光降解是由吸附机制引导的有关。然而,有时光催化剂的活性与吸附机理并不是线性相关的。本文研究了用统计近似法比较线性模型对ZnO-赫克托石(ZnO/CTMA/赫克托石)和tio2 -蒙脱土基材料光活性的评价。对该模型进行了光降解苯酚溶液的评价。probit模型的一些有益结果是:(1)保证了活性预测值在0-100%范围内;(2)很好地描述了吸附和光降解机制的相互作用。
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