基于显微组织观察、元素分布和粒度分析的Sn-0.7Cu强化机制研究

Yu Shen, Yumeng Ouyang
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引用次数: 1

摘要

Sn-0.7Cu是一种典型的电子封装用无铅焊料,但其强化机理尚不清楚。在本研究中,我们将找出添加0.7 wt.% Cu对锡基合金硬度增强的主要机理。观察到Cu-Sn IMC析出,Sn-0.7 cu的硬度高于纯Sn。EBSD取向图显示Sn-0.7 cu钎料中Sn的晶粒尺寸较大。结果表明,Cu6Sn5 IMC在Sn基体中析出,可以抵抗位错滑移,提高焊料的硬度。热时效后,Cu6Sn5 IMC的团簇使Sn-0.7Cu钎料的硬度降低了约20%。能够支持网状结构的Cu6Sn5分散是提高焊料强度的关键机制。
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A Study on Strengthening Mechanisms in Sn-0.7Cu via Microstructural Observation, Elemental Distribution, and Grain-Size Analysis
Sn-0.7Cu is a typical Pb-free solder for electronic packaging, but its strengthening mechanism has not been clear. In this study, we will figure out the main mechanisms for the hardness enhancement of the addition of the 0.7 wt.% Cu on the Sn matrix alloy. The precipitation of Cu-Sn IMC was observed, and the hardness of the Sn-0.7Cu was higher than that of pure Sn. EBSD orientation map shows the large grain size of Sn in the Sn-0.7Cu solder. That proves that the precipitation of the Cu6Sn5 IMC is in the Sn matrix that resists dislocation slips and enhances the hardness of the solder. After thermal aging, the cluster of Cu6Sn5 IMC induces the ~20% decrease in the hardness of the Sn-0.7Cu solder. That can support the net-like structure of the Cu6Sn5 dispersion is the critical mechanism to enhance the strength of the solder.
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