分子束外延生长的高效反向GaInAs太阳能电池用AlInAs异质结发射体

R. Oshima, T. Sugaya
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摘要

在III-V型太阳能电池中,通过采用后部异质结(RHJ)结构作为控制内置电位的手段来提高转换效率已经进行了大量的研究。本文将p型Al0.48In0.52As后异质结(RHJ)发射极应用于带隙为0.75 eV的Ga0.47In0.53As太阳能电池中。典型的RHJ太阳能电池结构由于pn界面和异质界面的位置相同,反向饱和电流密度(J0)增加。另一方面,在p-AlInAs发射极和n-GaInAs基底之间引入适当厚度的n-AlInAs间隔层可以分离每个界面位置,并且可以降低J0,从而改善VOC和FF。此外,优化后的RHJ太阳能电池采用了背面反射结构,由于促进了光捕获,其转换效率为15.38%,在目前文献报道的值中最高。
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AlInAs heterojunction emitter for highly efficient inverted GaInAs solar cells grown by molecular beam epitaxy
In III-V solar cells, much research has been conducted to improve the conversion efficiency by applying a rear heterojunction (RHJ) structure as a mean of controlling the built-in potential. In this work, a p-type Al0.48In0.52As rear heterojunction (RHJ) emitter was employed in Ga0.47In0.53As solar cells with 0.75 eV in bandgap grown by molecular beam epitaxy. A typical RHJ solar cell structure showed increase in reverse saturation current density (J0) since the positions of the pn interface and the heterointerface are the same. On the other hand, the introduction of an appropriate thicknesses of n-AlInAs spacer layer between p-AlInAs emitter and n-GaInAs base can separate each interface position and was found to reduce J0 leading to improved VOC and FF. In addition, the backside reflective structure was employed to optimized RHJ solar cells, showing the highest conversion efficiency of 15.38% among the reported values in the literature so far due to promoted light trapping.
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