Ag对Sn-Zn-Bi无铅钎料与铜基体金属间化合物及连接强度的影响

N. A. Jasli, H. A. Hamid, R. Mayappan
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引用次数: 0

摘要

研究了Ag对液态时效下Sn-Zn-Bi基合金金属间化合物形成及接头强度的影响。Sn-8Zn-3Bi和(Sn-8Zn-3Bi)-1Ag无铅钎料在铜基体上反应生成金属间化合物。用扫描电镜(SEM)观察了相的形貌,并用能量色散x射线(EDX)估计了相的元素组成。结果表明,Sn-8Zn-3Bi钎料与Cu衬底反应形成Cu5Zn8金属间化合物。另一方面,当钎料中添加1%的Ag时,形成Cu3Sn和Cu6Sn5 IMC。Cu5Zn8金属间化合物的形貌呈扁平状,而Cu3Sn和Cu6Sn5则呈扇形。在Sn-Zn-Bi钎料中添加Ag可以提高焊点的剪切强度。认为Cu- sn的扇形形态有助于(Sn-8Zn-3Bi)-1Ag/Cu接头的强化。
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Effect of Ag addition on the intermetallic compound and joint strength between Sn-Zn-Bi lead free solder and copper substrate
This study investigated the effect of Ag addition on the formation of intermetallic compounds and joint strength of the Sn-Zn-Bi based alloys under liquid state aging. The intermetallic compounds were formed by reacting Sn-8Zn-3Bi and (Sn-8Zn-3Bi)-1Ag lead free solders on copper substrate. Scanning electron microscope (SEM) was used to see the morphology of the phases and energy dispersive x-ray (EDX) was used to estimate the elemental compositions of the phases. It was found that for Sn-8Zn-3Bi solder reacting with Cu substrate, the Cu5Zn8 intermetallic was formed. On the other hand, when 1% Ag was added into the solder, the Cu3Sn and Cu6Sn5 IMC were formed. The morphology of the Cu5Zn8 intermetallic was flat whereas for Cu3Sn and Cu6Sn5 were rather scallop. The addition of Ag into the Sn-Zn-Bi solder increases the shear strength of the solder joint. It is believed the scallop morphology of Cu-Sn contribute to strengthening the (Sn-8Zn-3Bi)-1Ag/Cu joints.
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