砷在Si和Si/sub - 1-x/Ge/sub -x/涂层中的扩散比较

L. Zou, Z.G. Wang, D. Sun, T. Fan, X.F. Liu, J.W. Zhang
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引用次数: 0

摘要

研究了离子注入砷在松弛的Si/sub - 1-x/Ge/sub -x/ (x=0.90/spl sim/0.43)薄膜中的快速热退火,并比较了其在Si中的扩散。样品分析包括二次离子质谱的深度分析,以及扩频电阻探针测量的电学表征。砷化学浓度谱表明,砷在Si/sub - 1-x/Ge/sub -x/样品中RTA后的扩散行为与在Si中不同,且x较高的Si/sub - 1-x/Ge/sub -x/样品呈现出盒状的浓度依赖扩散曲线。Si/sub 0.57/Ge/sub 0.43/中电活性砷的最大浓度分别为3.0/spl倍/10/sup 19/和4.2/spl倍/10/sup 19/ cm/sup -3/,在950/spl℃和1050/spl℃下退火18 s,比砷注入Si的砷平衡溶解度极限低约一个数量级。
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Comparison of arsenic diffusion in Si and Si/sub 1-x/Ge/sub x/ epilayers
Rapid thermal annealing of ion implanted arsenic in relaxed Si/sub 1-x/Ge/sub x/ (x=0.90/spl sim/0.43) epilayers was studied and compared to diffusion in Si. Sample analysis included depth profiling by secondary-ion-mass spectroscopy, and electrical characterization employing spreading resistance probe measurement. Arsenic chemical concentration profiles indicated that the behavior of implanted As in Si/sub 1-x/Ge/sub x/ after RTA was different from that in Si, and the Si/sub 1-x/Ge/sub x/ samples with the higher x exhibited box-shaped, concentration-dependent diffusion profiles. The maximum concentrations of electrically active arsenic in Si/sub 0.57/Ge/sub 0.43/ were found to be 3.0/spl times/10/sup 19/ and 4.2/spl times/10/sup 19/ cm/sup -3/ for 18 second anneals at 950/spl deg/C and 1050/spl deg/C, respectively, which is about one order of magnitude lower than the arsenic equilibrium solubility limit for arsenic-implanted Si.
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