器件应用中氮化镓和氮化镓在硅上的溅射外延

A. Dadgar, F. Hörich, Ralf Borgmann, C. Lüttich, J. Bläsing, G. Schmidt, P. Veit, J. Christen, A. Strittmatter
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引用次数: 0

摘要

溅射外延是一种低成本的工艺,可以在比金属有机气相外延(MOVPE)更低的生长温度下进行大面积沉积,并且可以简化与Si CMOS技术的集成。我们用反应磁控溅射技术在Si(111)衬底上生长了高质量的氮化镓外延层结构。通过优化Si(111)衬底上的成核和生长,获得的AlN层具有与MOVPE生长样品相当的扭曲和倾斜值,并且具有非常低的表面粗糙度,没有任何柱状结构。通过Al和Ga的共溅射,研究了AlGaN的整个组成范围。薄的未掺杂缓冲层样品显示出高击穿场强,远高于1×106 V/cm,这是FET应用的先决条件。我们还报道了反应溅射的材料组合,这在很大程度上是不可接近的MOVPE,例如过渡金属氮化物和AlScN。
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Sputter epitaxy of AlN and GaN on Si for device applications
Sputtering epitaxy is a low cost process allowing large area deposition at lower growth temperatures than metalorganic vapour phase epitaxy (MOVPE) and may ease e.g. integration with Si CMOS technology. We present high quality AlN and GaN epitaxial layer structures grown on Si(111) substrates by reactive magnetron sputtering. By optimizing nucleation and growth on Si(111) substrates AlN layers are obtained with twist and tilt values comparable to MOVPE grown samples and with very low surface roughness free of any columnar structure. Also the entire compositional range of AlGaN has been addressed by co-sputtering of Al and Ga. Thin undoped buffer layer samples show high breakdown field strengths well above 1×106 V/cm which is prerequisite for FET applications. We also report on reactive sputtering of material combinations that are largely inaccessible to MOVPE, e.g., transition metal nitrides and AlScN.
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