由纳米纤维素和碳纳米管制成的可打印和一次性超级电容器

S. Tuukkanen, S. Lehtimäki, F. Jahangir, Antti-Pekka Eskelinen, Donald Lupo, Sami Franssila
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引用次数: 23

摘要

超级电容器是一种很有前途的能量存储设备,其电容比传统电容器高得多,比锂电池具有更高的功率密度和更长的循环寿命。我们报道了用溶液处理的碳纳米管(CNT)复合材料作为活性电极,纳米纤维素(NC)作为分离器制成的可打印和一次性超级电容器。使用高多孔性和导电性的碳纳米管薄膜作为电极材料,消除了对集流器的需要。NC是一种坚固耐用的隔膜材料,用于替代传统的聚合物隔膜膜。根据工业标准,采用恒流放电法对超级电容器进行了表征。1.8 cm2器件的电容为14.9-16.5 mF (7.4-9.1 mF/cm2或2.4-2.9 F/g),等效串联电阻(ESR)为74-155 Ω。这种由安全环保材料制成的低成本储能装置在自主智能和一次性低端产品方面具有明显的应用前景。
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Printable and disposable supercapacitor from nanocellulose and carbon nanotubes
Supercapacitors are promising energy storage devices providing capacitance much higher than conventional capacitors and higher power density and longer cycle life than Li-batteries. We report printable and disposable supercapacitors fabricated from solution-processed carbon nanotube (CNT) composite material as active electrodes and nanocellulose (NC) as a separator. Use of a highly porous and electrically conducting CNT film as electrode materials eliminates the need of current collector. NC is a robust separator material used instead of conventional polymer separator films. Supercapacitor characterization was done with a galvanostatic discharge method according to an industrial standard. The capacitance of 1.8 cm2 devices was 14.9-16.5 mF (7.4-9.1 mF/cm2 or 2.4-2.9 F/g) and equivalent series resistance (ESR) 74-155 Ω. This type of low-cost energy storage devices fabricated from safe and environmentally friendly materials have obvious applications in autonomous intelligence and disposable low-end products.
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