铝熔化对二极管完整性的影响

A. Kamgar, R. Knoell, F. Baiocchi, K. Orlowsky, K. Cheung, R. Liu
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摘要

研究了Al熔化后Al/barrier/CoSi/sub - 2/结的完整性。熔融是通过在快速热退火系统中辐照硅片完成的。研究了三种类型的势垒:TiN、W:Ti和W:Ti/TiN双分子层。结漏测量表明,W:Ti/TiN双分子层优于其他两种,并且可以承受比Al熔化温度高出至少60℃的温度,持续时间不超过1秒。通过卢瑟福后向散射、x射线衍射和蚀刻实验来确定熔化后各层之间相互作用的程度。作者发现,对于W:Ti势垒,当Al熔化时,W很容易与Al和Si反应,形成三元合金W(Al,Si)/sub 2/,可能还有其他相,包括Co作为成分。另一方面,TiN有效地阻止了Al和W与Co和Si的反应
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Impact of Al melting on diode integrity
The integrity of Al/barrier/CoSi/sub 2/ junctions subjected to Al melting was studied. Melting was accomplished by irradiating Si wafers in a rapid thermal anneal system. Three types of barrier were studied: TiN, W:Ti, and a bilayer of W:Ti/TiN. Junction leakage measurements indicated that the W:Ti/TiN bilayer was superior to the other two and that it withstood temperatures at least 60 degrees C higher than the Al melting temperature for one second or less. Rutherford backscattering, X-ray diffraction, and etchback experiments were performed to determine the extent of interaction between the various layers after the melt. The authors found that for the W:Ti barrier, upon melting of Al, W reacted readily with Al and Si, forming the ternary alloy, W(Al,Si)/sub 2/, and possibly other phases including Co as a constituent. TiN on the other hand effectively prevented the reaction of Al and W with Co and Si.<>
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