Cu-Cu热压键合的建模

K. Shie, Dinh-Phuc Tran, A. Gusak, K. Tu, Hung-Che Liu, Chih Chen
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引用次数: 1

摘要

提出了一个简单的键合模型,将键合时间与表面粗糙度、温度、压力和晶界扩散率等参数联系起来。理论键合时间定义为键合面积达到表面积95%所需的时间。Cu-Cu直接结合是通过表面蠕变机制完成的,可分为4个阶段:表面接触和塑性变形阶段、孤立空洞和晶界形成阶段、界面空洞成熟阶段和晶粒长大过程中界面消除阶段。在本研究中,我们建立了第二阶段粘接的表面蠕变模型。驱动力是压力梯度,压力梯度通过晶界和表面扩散触发Cu原子填充键合界面的空隙。这是由系统中吉布斯自由能的释放驱动的。我们考虑了模型的关键参数,包括表面粗糙度、键合温度和压力。利用这样的动力学模型,我们能够估计出理论键合时间作为表面粗糙度、晶界扩散系数、温度和压力的函数。结果表明,表面粗糙度和取向对键合时间有重要影响。在200℃和0.5 MPa下,表面粗糙度为10 nm的Cu薄膜的理论键合时间为104 s。当表面粗糙度降低到1.0 nm时,预计键合时间为10 s。
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Modeling of Cu-Cu Thermal Compression Bonding
A simple bonding model is proposed to correlate the bonding time with some parameters such as surface roughness, temperature, pressure, and grain boundary diffusivity. The theoretical bonding time is defined as the time required for the bonding area to reach 95% of the surface area. Cu-Cu direct bonding is accomplished through the surface creep mechanism, which are divided into four stages, surface contact and plastic deformation, isolated void and grain boundary formation, interfacial void ripening, and interface elimination by grain growth. In this study, we established a surface creep model for the second bonding stage. The driving force is a pressure gradient, which triggers Cu atoms to fill voids at the bonding interface via grain boundary and surface diffusion. This is driven by the release of Gibbs free energy in the system. We took the critical parameters, including surface roughness, bonding temperature, and pressure into account of the model. Using such a kinetic model, we are able to estimate the theoretical bonding time as functions of surface roughness, grain boundary diffusivity, temperature, and pressure. The results indicate that surface roughness and orientation play critical roles on the bonding time. The theoretic bonding time is estimated as 104 s for the Cu films with a surface roughness of 10 nm bonded at 200 °C and 0.5 MPa. As the surface roughness is reduced to 1.0 nm, a bonding time of 10 s is predicted.
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