具有两个最大共沸体的体系的挥发阶研究

Guilian Liu, Lijun Wang
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引用次数: 0

摘要

在具有两个最大共沸物的体系中,根据不同的等挥发谱线可以得到不同的挥发阶数。本文根据Aspen Plus的严格模拟,确定了具有两个最大共沸体的体系的挥发阶,并与等挥发谱线确定的体系的挥发阶进行了比较。结果表明,具有两个最大共沸物和两条等挥发谱线的体系存在两个蒸馏区,根据等挥发谱线可以确定其挥发顺序。在此基础上,提出了识别波动顺序的规则。并将其应用于两种不同的情况,结果表明该规则准确、简单,可方便地应用。
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Study on the volatility order of systems with two maximum azeotropes
In systems with two maximum azeotropes, different volatility orders can be obtained according to different isovolatility line. In this paper, the volatility orders of systems with two maximum azeotropes are identified according to the rigorous simulation of Aspen Plus, and are compared with that identified according to the isovolatility lines. The results show that, there are two distillation regions in systems with two maximum azeotropes and two isovolatility lines, the volatility order in them can be identified according to the isovolatility line lying in them. Based on this, the rule for identifying the volatility order is proposed. And, it is applied to two different cases, and the results shows that this rule is accurate, simple and can be applied convienently.
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