Fe2O3-SiO2-CTAB透明纳米复合膜的制备与研究

Lin Li, Lanfang Yao, Shuo Wang, Ruiqing Xu, Linlin Tian, X. Fang
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摘要

以表面活性剂十六烷基三甲基溴化铵(CTAB)为模板剂,四乙氧基硅烷(TEOS)为原料,硝酸铁Fe(NO3)3·9H2O为铁源材料,采用两步酸催化和溶胶-凝胶法制备了Fe2O3-SiO2-CTAB透明纳米复合薄膜。利用紫外可见光谱、傅里叶红外光谱和振动样品磁强计(VSM)研究了薄膜的光学性质、结构和磁性。经高温处理的Fe2O3-SiO2-CTAB纳米复合薄膜的透明度超过玻璃基板。膜的饱和磁化强度(Ms)随处理温度的升高而增大。磁化性能测试表明,Fe2O3-SiO2-CTAB纳米复合膜具有正常的铁磁行为。实验还表明,CTAB对Fe2O3-SiO2-CTAB复合薄膜的光学和磁性能起关键作用。
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Preparation and investigation of Fe2O3-SiO2-CTAB transparent nano-composite films
Fe2O3-SiO2-CTAB transparent nano-composite films were prepared by means of a two-step acid-catalyzed method and sol-gel process using surfactant cetyltrimethylammonium bromide (CTAB) as template and tetraethoxysilane (TEOS) as the starting material, iron nitrate Fe(NO3)3·9H2O as iron source material. Optical properties, structural and magnetic characteristics of the films were investigated by UV-visible spectra, FT-IR spectra and vibrating sample magnetometer (VSM). The transparency of the high temperature treated Fe2O3-SiO2-CTAB nano-composite films exceeds the glass substrate. It is also found that the saturation magnetization (Ms) of the films increases with the treating temperature. The magnetization measurements reveal that Fe2O3-SiO2-CTAB nano-composite films display normal ferromagnetic behaviors. It is also shown that the CTAB plays a key role in the optical and magnetic properties of Fe2O3-SiO2-CTAB composite films.
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