超低水分聚合物粘接模用胶粘剂的研制

M. Nguyen, I. Chien
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引用次数: 3

摘要

研制了一种基于改性烯烃热固性聚合物的新型模具贴附材料。由于其疏水分子结构,吸湿性本来就很低。例如,在85/spl°/C/85% RH/168小时下,吸湿率小于0.05%。即使在HAST测试(150/spl℃/85% RH/168小时)中,水分含量仅为0.1%。该烯烃聚合物被配制成一种低应力、导电和导热的膏状粘合剂。它的其他主要特点包括良好的加工性,较少的树脂溢出和低温固化。使用208 LD PQFP封装和标准环氧树脂成型化合物对新的模具附件候选件进行了评估。这种包装通过了3级防潮可靠性测试。在JEDEC一级,在模具复合界面处仍然存在封装裂纹和分层。然而,没有观察到模具附着分层。这些研究清楚地表明,需要用低吸湿性聚合物代替传统的环氧树脂,用于模具附着和封装,以生产对水分不敏感的封装。总之,新的烯烃热固性胶粘剂已经显示出许多模具附加应用的希望。这些材料将为先进器件封装提供重要的工艺和可靠性改进。
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Development of an ultra low moisture polymer adhesive for die attach applications
A new type of die attach material based on a modified olefin thermoset polymer has been developed. Due to its hydrophobic molecular structure, moisture absorption is inherently very low. For example, it absorbs less than 0.05% moisture at 85/spl deg/C/85% RH/168 hrs. Even in HAST test (150/spl deg/C/85% RH/168 hrs.), moisture content is only 0.1%. The olefinic polymer is formulated as a low stress, electrical and thermally conducting paste adhesive. Its other principal features include good processability, less resin bleed and low temperature cure. The new die attach candidates were evaluated using 208 LD PQFP packages with standard epoxy molding compounds. This type of package passed moisture reliability tests at level 3. At JEDEC level 1, there were still package cracks and delaminations at the mold compound interfaces. However, no die attach delamination was observed. These studies clearly demonstrated the need for replacing conventional epoxies with low moisture absorbing polymers for die attachment and encapsulation in order to produce moisture insensitive packages. In summary, the new olefinic thermoset adhesives have shown promise for many die attach applications. These materials will provide important process and reliability improvement for advanced device packaging.
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