溶胶-凝胶法制备五氧化二钒多孔膜的光学和电化学性能

Shixiong She, Guang-ming Wu, Huiyu Yang, Jun Shen, G. Gao
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摘要

V2O5薄膜,特别是具有纳米和微结构的钒氧化物薄膜,是锂离子电池和电荷存储器件的良好正极材料。采用浸渍-溶胶-凝胶法制备了不同孔隙率的V2O5薄膜。将V2O5粉末按一定比例溶于苯甲醇和异丙醇,制备了V2O5溶胶。利用红外光谱和椭偏仪对薄膜的光学性能和孔隙率进行了表征。用时间电位法(CP)和循环伏安法(CV)记录了电化学表征。此外,研究表明,V2O5薄膜的多孔结构对薄膜的稳定性和可逆性有影响。
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Optical and electrochemical properties of vanadium pentoxide porous film prepared by sol-gel technique
Thin films of V2O5, especially vanadium oxide films with nano- and micro-structures, perform well as cathode material for Li ion batteries and charge storage devices. Thin films of V2O5 with different porosity were obtained by dip-coating sol-gel technique. V2O5 sols were prepared by dissolution of V2O5 powder in benzyl alcohol and isopropyl alcohol in proper proportion. Optical property and porosity of films were characterized by FTIR and ellipsometer. Electrochemical characterization was recorded by chronopotentiometry(CP) and cyclic voltammetry(CV). Furthermore, the study shows that the porous structures of V2O5 films had an effect on the stability and reversibility of the films.
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